典型道路路邊空氣顆粒物及無機(jī)元素特征分析
發(fā)布時(shí)間:2019-07-28 15:03
【摘要】:于2015年春、夏季,在天津市選取4條不同等級道路進(jìn)行路邊空氣顆粒物(PM_(2.5)和PM_(10))采集,并分析其中16種無機(jī)元素.結(jié)果表明,春季PM_(2.5)和PM_(10)的平均濃度顯著高于夏季.路邊環(huán)境中PM_(2.5)/PM_(10)低于非路邊環(huán)境中空氣顆粒物比值,且次干道和快速路分別在PM_(2.5)和PM_(10)中污染最嚴(yán)重.元素濃度分析顯示,PM_(2.5)和PM_(10)中Si、Al、Ca等地殼元素濃度最高,次干道和快速路受人為元素影響較大,外環(huán)路所受影響較小;富集因子(PM_(2.5)和PM_(10))分析結(jié)果顯示,Pb、Zn、Cu、Sb、Sn和Cd的EF10,是路邊環(huán)境中富集程度較高的元素.通過Kruskal-Wallis H檢驗(yàn),PM_(2.5)中各元素富集因子在4條道路上存在顯著性差異,次干道受機(jī)動(dòng)車污染較嚴(yán)重.PM_(2.5)和PM_(10)中因子分析結(jié)果有一定差異,PM_(2.5)分析結(jié)果顯示采樣期間該區(qū)域主要污染源有開放源(土壤塵、揚(yáng)塵、道路塵及建筑塵)、機(jī)動(dòng)車排放源(尾氣和非尾氣源)、燃燒源和工業(yè)源,其中機(jī)動(dòng)車排放源在人為源污染中占比最高.
[Abstract]:In spring and summer of 2015, four different grades of roads were selected in Tianjin to collect roadside air particles (PM_ (2.5) and PM_ (10), and 16 inorganic elements were analyzed. The results showed that the average concentrations of PM_ (2.5) and PM_ (10) in spring were significantly higher than those in summer. The ratio of PM_ (2.5) / PM_ (10) in roadside environment was lower than that in non-roadside environment, and the pollution of subtrunk road and expressway was the most serious in PM_ (2.5) and PM_ (10), respectively. The results of elemental concentration analysis showed that the concentration of Si,Al,Ca and other crust elements in PM_ (2.5) and PM_ (10) was the highest, the secondary trunk road and expressway were greatly affected by artificial elements, but the outer loop was less affected. The results of enrichment factor (PM_) and PM_ (10) analysis showed that the EF10, of Pb,Zn,Cu,Sb,Sn and Cd was the element with high enrichment in roadside environment. Through Kruskal-Wallis H test, there were significant differences in the enrichment factors of each element in PM_ (2.5) on four roads, and the secondary main roads were seriously polluted by motor vehicles. The results of factor analysis in PM_ (2.5) and PM_ (10) were different. The results of PM_ (2.5) analysis showed that there were open sources (soil dust, road dust and building dust) in this area during the sampling period. Motor vehicle emission sources (exhaust and non-tail gas sources), combustion sources and industrial sources, among which motor vehicle emission sources account for the highest proportion of man-made sources of pollution.
【作者單位】: 南開大學(xué)環(huán)境科學(xué)與工程學(xué)院城市交通污染防治研究中心;
【基金】:國家科技支撐計(jì)劃項(xiàng)目(2014BAC16B03) 科技部科技基礎(chǔ)性工作專項(xiàng)(2013FY112700-02)
【分類號(hào)】:X513
[Abstract]:In spring and summer of 2015, four different grades of roads were selected in Tianjin to collect roadside air particles (PM_ (2.5) and PM_ (10), and 16 inorganic elements were analyzed. The results showed that the average concentrations of PM_ (2.5) and PM_ (10) in spring were significantly higher than those in summer. The ratio of PM_ (2.5) / PM_ (10) in roadside environment was lower than that in non-roadside environment, and the pollution of subtrunk road and expressway was the most serious in PM_ (2.5) and PM_ (10), respectively. The results of elemental concentration analysis showed that the concentration of Si,Al,Ca and other crust elements in PM_ (2.5) and PM_ (10) was the highest, the secondary trunk road and expressway were greatly affected by artificial elements, but the outer loop was less affected. The results of enrichment factor (PM_) and PM_ (10) analysis showed that the EF10, of Pb,Zn,Cu,Sb,Sn and Cd was the element with high enrichment in roadside environment. Through Kruskal-Wallis H test, there were significant differences in the enrichment factors of each element in PM_ (2.5) on four roads, and the secondary main roads were seriously polluted by motor vehicles. The results of factor analysis in PM_ (2.5) and PM_ (10) were different. The results of PM_ (2.5) analysis showed that there were open sources (soil dust, road dust and building dust) in this area during the sampling period. Motor vehicle emission sources (exhaust and non-tail gas sources), combustion sources and industrial sources, among which motor vehicle emission sources account for the highest proportion of man-made sources of pollution.
【作者單位】: 南開大學(xué)環(huán)境科學(xué)與工程學(xué)院城市交通污染防治研究中心;
【基金】:國家科技支撐計(jì)劃項(xiàng)目(2014BAC16B03) 科技部科技基礎(chǔ)性工作專項(xiàng)(2013FY112700-02)
【分類號(hào)】:X513
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