本文選題：模板硼酸鹽 + 溶劑熱合成�。� 參考：《廣東工業(yè)大學》2015年碩士論文

【摘要】：本論文采用傳統(tǒng)的水熱／溶劑熱法和溶液法,以硼酸、3-硝基苯硼酸、金屬鹽、DMF以及有機胺為原料,成功合成了四種模板硼酸鹽。用X-射線單晶衍射儀對四種化合物進行晶體結(jié)構(gòu)表征,對四種化合物進行了元素分析、紅外、熱重、X-射線粉末衍射四種基本的測試分析。同時對化合物1進行變溫熱處理,并對處理后的樣品進行了X-射線粉末衍射、紅外以及熒光光譜分析,探討了熱處理對化合物的熒光性質(zhì)的影響；研究了化合物2和4的鐵電性,在硼酸鹽領(lǐng)域第一次對化合物4進行了薄膜鐵電測試；化合物3的是少見的手性的沸石結(jié)構(gòu)硼酸鹽。主要研究內(nèi)容如下：化合物1屬于三斜晶系,分子式為[C9H14N][B506(OH)4],空間群為P1(No.2),晶胞參數(shù)為：1:9.2635(19)A,b=9.7473(19)A,c=9.806(2)A,α=73.12 (3)°, β=83.82(3)°,β=69.59(3).,經(jīng)過200℃熱處理的樣品在波長為379nm激發(fā)光的激發(fā)下發(fā)出437nm的光�；衔�2屬于單斜晶系,分子式為：Ni(en)3·Hen·[B9013(OH)4]·H20,空間群為Pn(NO.6).晶胞參數(shù)為：a=10.9982(18)A,b=10.8439(17)A,c=11.7551 (19)A, β:91.84(O)°,化合物2是目前報道的第一個多鐵性的模板硼酸鹽和第一個由不同結(jié)構(gòu)單元組合的手性鏈狀硼酸鹽�；衔�3屬于四方晶系,分子式為：Zn(1,3-DAP)[B407],空間群為P43212(No.96),晶胞參數(shù)為：a=8.670(4)A,b=8.670(4)A,c=12.722(13)A,α:90.00°, β=90.OO°,γ=90.00°,根據(jù)目前報道,化合物3是一種少見的螺旋狀硼酸鋅沸石骨架材料�；衔�4屬于單斜晶系,分子式為：[B506(OH)4][C6H15N2],空間群為：Cc(NO.9),晶胞參數(shù)為：a=9.786(4)A,b=20.930(9)A,c=14.577(6)A, a=90.00°,β=94.406(5)°,γ=90.00°,通過優(yōu)化實驗方案,成功制備了化合物4的薄膜并對其進行了薄膜鐵電表征。
[Abstract]:In this paper, four kinds of template borates were successfully synthesized by hydrothermal / solvothermal method and solution method, using borate 3-nitrophenyl boric acid, metal salt DMF and organic amine as raw materials. The crystal structure of four compounds was characterized by X-ray single crystal diffractometer. The four compounds were characterized by elemental analysis, IR and thermogravimetric X-ray powder diffraction. At the same time, compound 1 was heat-treated at varying temperature, and the treated samples were analyzed by X-ray powder diffraction, IR and fluorescence spectra. The effects of heat treatment on the fluorescence properties of the compounds were discussed. The ferroelectric properties of compounds 2 and 4 were studied and the thin film ferroelectric test of compound 4 was carried out for the first time in the field of borates. The main contents of the study are as follows: compound 1 belongs to a triclinic system, its molecular formula is [C9H14N] [B506(OH)4], the space group is P1O No. 2N, and the unit cell parameters are: 1: 1: 9: 2635 / 19 A / C 9.7473C / C 9.806U / 2C, 偽 / C = 73.123) 擄, 尾 = 83.823) 擄, 尾 = 69.59N ~ (3N) 路, and the samples after heat treatment at 200 鈩，

本文編號：1875856