納米碳基材料由于具有低密度、高強度、環(huán)境友好、結(jié)構(gòu)可控、表面易于修飾等優(yōu)點,成為了一類非常理想的表面分子印跡基質(zhì)材料。相應(yīng)的納米碳基表面分子印跡聚合物（C-SMIPs）吸附劑,對于實現(xiàn)液相環(huán)境體系中的有機小分子污染物的選擇性吸附脫除與富集回收取得了令人滿意的效果。本綜述對該應(yīng)用背景下近五年來的不同維度C-SMIPs進(jìn)行了歸納總結(jié)。不僅發(fā)現(xiàn)C-SMIPs吸附能力的下限更容易受基質(zhì)材料的影響,其上限則更多地取決于印跡層的構(gòu)建情況,以多孔納米炭球和氧化石墨烯為基質(zhì)的C-SMIPs通常具有較高的吸附容量,其中氧化石墨烯基SMIPs通常具有較高的吸附效率。同時本綜述還推斷出C-SMIPs對于目標(biāo)分子吸附的本質(zhì)是固液界面間的物理性吸附,解決了長時間以來令人困擾的對吸附過程定性的爭議。另外,通過本綜述的探討分析,可以為接下來深入研究C-SMIPs的基質(zhì)篩選、印跡方法、吸附條件選擇等提供一些可借鑒的理論和實踐經(jīng)驗,從而不斷推進(jìn)C-SMIPs的研發(fā)和應(yīng)用。 

【文章來源】：新型炭材料. 2020,35(05)北大核心EISCICSCD

【文章頁數(shù)】：27 頁

【文章目錄】：
1 Introduction
2 C-SM IPs for organic compound ad-sorption
    2.1 0D and q-0D nano-carbon based SMIPs
    2.2 1D nano-carbon based SMIPs
    2.3 2D nano-carbon based SMIPs
    2.4 Other carbon-based C-SMIPs
3 The influence of nano-carbon sup-port on the C-SM IPs
    3.1 Effect of nano-carbon support on the micro-structure of C-SMIPs
    3.2 Effect of nano-carbon support on the adsorp-tion performance of C-SMIPs
        3.2.1 Effect of nano-carbon support on adsorption capacity
        3.2.2 Effect of nano-carbon support on the imprint-ing factor
        3.2.3 Effect of nano-carbon support on equilibrium time
        3.2.4 Effect of nano-carbon support on relative se-lectivity factor
    3.3 Effect of nano-carbon support on the adsorp-tion kinetic,isothermal,and thermodynamic of C-SMIPs
        3.3.1 Effect of nano-carbon support on the adsorp-tion kinetic
        3.3.2 Effect of nano-carbon support on the adsorp-tion isothermal
        3.3.3 Effect of nano-carbon support on the adsorp-tion thermodynamic
    3.4 Adsorption mechanism of C-SMIP adsorbents
4 Conclusions and perspectives


【參考文獻(xiàn)】：
期刊論文
[1]用于焦化廢水脫除苯酚的親水性多孔炭納米球基表面分子印跡聚合物的制備（英文）[J]. 張瑤,秦蕾,崔燕,劉偉峰,劉旭光,楊永珍.  新型炭材料. 2020(03)
[2]一鍋水熱法制備全氟辛磺酸鹽印跡碳微球及其吸附性能研究[J]. 于慧,陳燕飛,郭會琴,馬文天,李晶,周水根,林森,顏流水,李可心.  分析化學(xué). 2019(11)



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