用溶劑熱法設(shè)計(jì)、合成了4個(gè)金屬-有機(jī)配合物[Mn（L¹）₄（OH）₂]（1）,{[MnL¹（H₂O）₄]SO₄}_n（2）,[CdL²（NO₃）₂]_n（3）和{[Co（L²）₂]（PF₆）₂}_n（4）,（L¹=3,6-二（N-咪唑基）噠嗪,L²=3,6-二（N-苯并咪唑基）噠嗪）,并通過元素分析、紅外、X射線單晶衍射對(duì)配合物結(jié)構(gòu)進(jìn)行了表征,測(cè)試結(jié)果表明配合物1具有單核結(jié)構(gòu),2為一維鏈結(jié)構(gòu),配合物3和4均為二維網(wǎng)狀結(jié)構(gòu)。此外,對(duì)配合物3和4的固態(tài)熒光性能及光催化的性能做了進(jìn)一步研究。 

【文章來源】：無機(jī)化學(xué)學(xué)報(bào). 2016,32(05)北大核心SCICSCD

【文章頁(yè)數(shù)】：9 頁(yè)

【文章目錄】：
0 Introduction
1 Experimental
    1.1 Materials and general methods
    1.2 Synthesis of ligand L1
    1.3 Synthesis of ligand L2
    1.4 Synthesis of complex 1
    1.5 Synthesis of complex 2
    1.6 Synthesis of complex 3
    1.7 Synthesis of complex 4
    1.8 Determination of photocatalytic activity
    1.9 Structure determination
2 Results and discussion
    2.1 Structure description of 1
    2.2 Structure description of 2
    2.3 Structure description of 3
    2.4 Structure description of 4
    2.5 Thermogravimetric analysis
    2.6 XRPD patterns
    2.7 Luminescent properties
    2.8 Photocatalytic activity
3 Conclusions



本文編號(hào)：3116080