【摘要】：合成并通過X射線單晶衍射、元素分析及紅外光譜表征了配合物[Ni(L)_2](1)和[Cd(HL)(CH_3OH)(NO_3)_2](2)的結(jié)構(gòu)(HL為2-乙酰吡嗪縮肼基甲酸甲酯)。單晶衍射結(jié)果表明,配合物1中,Ni(Ⅱ)離子與來自2個陰離子配體L-的N_2O電子供體配位,形成扭曲的八面體配位構(gòu)型。在配合物2中,Cd(Ⅱ)離子擁有雙帽三棱柱配位構(gòu)型,與1個中性配體HL,2個雙齒配位硝酸根和1分子甲醇配位。此外還研究了配合物1和2的熒光及熱性質(zhì)。
[Abstract]:Synthesis and diffraction of X-ray single crystals, The structures of the complexes [Ni (L) _ 2] (1) and [Cd (HL) (CH_3OH) (NO_3) _ 2] (2) were characterized by elemental analysis and IR spectra. The results of single crystal diffraction show that the, Ni (鈪，

本文編號：2405790