【摘要】：該文對(duì)辣根過(guò)氧化物酶(HRP)催化聚合去除水中雙酚A(BPA)進(jìn)行實(shí)驗(yàn)研究,考察[H_2O_2]∶[BPA]摩爾比、酶活力和腐殖酸(HA)濃度對(duì)BPA去除的影響。結(jié)果表明,提高過(guò)氧化氫濃度和酶活力能夠提高BPA去除率,同時(shí)降低水中中間產(chǎn)物A的濃度。在[BPA]10 mg/L、[HRP]0.2 U/mL、[H_2O_2]∶[BPA]為1∶1,pH 7和25℃的條件下反應(yīng)30 min,當(dāng)水中存在2~10 mg/L HA情況下,BPA去除率從62.2%提高至90%以上。推測(cè)機(jī)理如下:加入適量的HA后,HA與BPA發(fā)生交叉偶聯(lián)反應(yīng),增大BPA去除率,當(dāng)HA加入量過(guò)大后,HA可能發(fā)生自聚合反應(yīng),對(duì)BPA與HA交叉偶聯(lián)反應(yīng)產(chǎn)生競(jìng)爭(zhēng)作用。
[Abstract]:The effects of [H_2O_2]: [BPA] molar ratio, enzyme activity and (HA) concentration of humic acid on the removal of BPA from water by catalytic polymerization of horseradish peroxidase (HRP) with bisphenol A (BPA) were studied. The results showed that increasing the concentration of hydrogen peroxide and enzyme activity could increase the removal rate of BPA and decrease the concentration of intermediate product A in water. When [BPA] 10 mg/L, [HRP] 0.2 U / mL, [H_2O_2]: [BPA] = 1: 1, pH 7 and 25 鈩，

本文編號(hào)：2376995