【摘要】：有機硼化合物在合成化學(xué)、材料科學(xué)、生命健康等領(lǐng)域都有廣泛應(yīng)用,因此有機硼化合物的合成一直是研究熱點.目前,催化C—B鍵形成反應(yīng)通常使用聯(lián)硼酸頻哪醇酯(B2Pin2)、頻哪醇硼烷(HBPin)、兒茶酚硼烷(HBCat)等作為硼試劑.相比于傳統(tǒng)的硼試劑,硼烷與胺、膦或N-雜環(huán)卡賓等強Lewis堿的加合物(統(tǒng)稱為穩(wěn)定硼烷加合物)具有易于合成、穩(wěn)定性高、易操作等特點,其作為硼試劑參與的有機硼化合物的合成最近受到越來越多的關(guān)注,已被成功用于烯(炔)烴的硼氫化、C—H鍵硼化、卡賓對B—H鍵的插入、硼自由基串聯(lián)環(huán)化、取代等反應(yīng)中,為有機硼化合物的合成提供了新的思路和方法.以反應(yīng)類型為線索,系統(tǒng)綜述了穩(wěn)定硼烷加合物在有機硼化物合成中的應(yīng)用研究進展.
[Abstract]:Organic boron compounds have been widely used in synthetic chemistry, material science, life and health, so the synthesis of organic boron compounds has been a hot topic. At present, the catalytic C-B bond formation reaction usually uses the boron reagent, such as B2Pin2, HBPin, HBCat, etc. Compared with traditional boron reagents, the adducts of borane and amine, phosphine or N-heterocyclic carbene have the advantages of easy synthesis, high stability and easy operation. Recently, more and more attention has been paid to the synthesis of organic boron compounds as boron reagents, which have been successfully used in borohydride C-H bonds of alkenes, the insertion of B-H bonds by carbens, and the series cyclization of boron radicals. The substitution reaction provides a new idea and method for the synthesis of organic boron compounds. The application of stable borane adducts in the synthesis of organic boride was systematically reviewed based on the type of reaction.
【作者單位】： 南開大學(xué)化學(xué)學(xué)院元素有機化學(xué)研究所元素有機化學(xué)國家重點實驗室;天津化學(xué)化工協(xié)同創(chuàng)新中心;
【基金】：國家自然科學(xué)基金(Nos.21625204,21421062,21290182) 國家重點基礎(chǔ)研究發(fā)展計劃(973項目,No.2012CB821600) 教育部“111計劃”(No.B06005) 國家特支計劃資助項目~~
【分類號】：O627.31

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