本文選題：稀土 + 吸附��； 參考：《南昌大學》2017年碩士論文

【摘要】：本文針對稀土資源開采過程中出現(xiàn)的回收不徹底、浪費嚴重等現(xiàn)狀,以綠色環(huán)保化學理念為指導,以MCM-41為基體,成功制備兩種經(jīng)硅烷偶聯(lián)劑改性的新型中孔硅基材料。分別用于輕稀土離子La~(3+)、中稀土離子Gd~(3+)及重稀土離子Yb~(3+)的富集回收實驗。根據(jù)實驗結(jié)果,本文系統(tǒng)的探究了三種吸附劑對低濃度稀土離子的吸附及脫附行為。首先,采用水熱合成法,以正硅酸乙酯(TEOS)作為硅源,以十六烷基三甲基溴化銨(CTAB)作為模板劑,簡單高效的合成MCM-41分子篩,其BET孔徑及比表面積分別為2.94 nm、1114.8 m~2/g。通過加入APTES和MPTES這兩種偶聯(lián)劑,對其進行孔道內(nèi)修飾,分別制備出了經(jīng)胺基、巰基功能化的NH_2-MCM-41和SH-MCM-41介孔材料,其BET孔徑及比表面積分別為2.15 nm、956.2 m~2/g和2.10 nm、956.0 m~2/g。偶聯(lián)劑成功進入MCM-41基體內(nèi)部,實現(xiàn)了孔道內(nèi)表面修飾。其次,以合成的MCM-41、NH_2-MCM-41和SH-MCM-41為吸附劑,稀土離子La~(3+)、Gd~(3+)和Yb~(3+)為吸附質(zhì),對吸附單因素條件、等溫吸附、熱力學、動力學、吸附機理及再生性能進行探究。實驗表明:MCM-41吸附劑對稀土離子La~(3+)、Gd~(3+)和Yb~(3+)的最大吸附量分別為434.08 mg/g、418.42 mg/g和492.40 mg/g;Fe~(3+)、Al~(3+)、Ca2+、Mg2+及NH4+五種干擾離子對稀土離子吸附量的影響:三價離子能與稀土離子形成競爭吸附從而降低其吸附量,其他離子對其吸附量影響很小。胺基的最佳(以N計)接枝量是1.98%,NH_2-MCM-41對Yb~(3+)的最大吸附量為709.70mg/g。吸附過程符合Freundlich等溫吸附模型,動力學可以用準二級速率方程進行描述。巰基的最佳(以S計)接枝量是6.06%;SH-MCM-41對La~(3+)、Gd~(3+)和Yb~(3+)的飽和吸附量分別達到了560.56 mg/g、507.85 mg/g和540.68 mg/g。最后,分別以鹽酸、硝酸和檸檬酸作為解吸劑,對吸附劑的洗脫及再生性能進行探究。從綠色化學出發(fā),最佳解析條件是:2 mol/L的鹽酸溶液,解析1 h,SH-MCM-41吸附劑對La~(3+)、Gd~(3+)和Yb~(3+)初次解析率分別達到了93.4%、92.1%和95.3%左右;重復使用4次,吸附劑對稀土離子的吸附率均保持在80%以上,說明合成的吸附劑有良好的水熱穩(wěn)定性,可循環(huán)再生,節(jié)約吸附成本。
[Abstract]:In this paper, two new mesoporous silicon-based materials modified by silane coupling agent were successfully prepared under the guidance of green environmental chemical idea and MCM-41 matrix in view of the incomplete recovery and serious waste during the process of rare earth resource exploitation. It has been used for the enrichment and recovery experiments of light rare earth ions Lahuo 3, medium rare earth ions Gdl3) and heavy rare earth ions Ybt3), respectively. Based on the experimental results, the adsorption and desorption behavior of three kinds of adsorbents for rare earth ions with low concentration were systematically investigated. Firstly, using tetraethyl orthosilicate (TEOS) as silicon source and cetyltrimethylammonium bromide (CTAB) as template, MCM-41 molecular sieve was synthesized by hydrothermal method. The BET pore size and specific surface area of MCM-41 molecular sieve were 2.94 nm and 1114.8 mg / g, respectively. By adding APTES and MPTES, the mesoporous materials of NH2-MCM-41 and SH-MCM-41 were prepared. The pore size and specific surface area of BET were 2.15 nm ~ 956.2 m ~ (2 / g) and 2.10 nm ~ 956.0 m ~ (-2 / g), respectively, and the mesoporous materials of NH2-MCM-41 and SH-MCM-41 were prepared. The coupling agent successfully entered the MCM-41 matrix and realized the inner surface modification of the pore channel. Secondly, using the synthesized MCM-41 and SH-MCM-41 as adsorbents, rare earth ions Lazhu3 (Gddf3) and Ybc3) as adsorbents, the adsorption conditions, isotherms, thermodynamics, kinetics, adsorption mechanism and regeneration properties of MCM-41 and SH-MCM-41 were investigated. The experimental results show that the maximum adsorption capacity of the adsorbents for rare earth ions Laohou 3 (GdDH3) and Ybn3) are 434.08 mg / g ~ 418.42 mg/g and 492.40 mg / g / g ~ (3) C ~ (2 +) respectively. The effects of five kinds of interference ions, such as Ca ~ (2 +), mg _ (2) and NH _ 4, on the adsorption capacity of rare earth ions are as follows: the three valence ions can compete with the rare earth ions in the adsorption capacity of rare earth ions: three valence ions can compete with rare earth ions in the adsorption capacity of rare earth ions. To reduce the amount of adsorption, Other ions have little effect on the adsorption capacity. The best grafting amount of amino group is 1.98% NH _ 2-MCM-41 and the maximum adsorption capacity is 709.70 mg 路g ~ (-1) 路m ~ (-1) 路min ~ (-1) 路min ~ (-1). The adsorption process is in accordance with Freundlich isothermal adsorption model and the kinetics can be described by quasi second order rate equation. The optimum grafting capacity of thiol group is 6.06g / g SH-MCM-41, and the saturated adsorption capacity of Ybf3 is 560.56 mg / g / g ~ 507.85 mg/g and 540.68 mg / g / g, respectively, and the saturated adsorption capacity of SH-MCM-41 is 560.56 mg / g / g and 540.68 mg / g / g, respectively, and the saturated adsorption capacity of thiol group is 560.56 mg / g / g and 540.68 mg / g / g, respectively. Finally, hydrochloric acid, nitric acid and citric acid were used as desorption agents to study the elution and regeneration of adsorbent. From green chemistry, the best analytical conditions are: 1 mol / L hydrochloric acid solution, 1 h SH-MCM-41 adsorbent for Lazhiyang3 (GdDX 3) and Ybzao 3) for the first time resolution rates of 93.4% and 95.3% respectively, and repeated use for 4 times, and the optimum analytical conditions are as follows: (1) the first analytical rate is about 93.1% and 95.3% respectively, and the first analytical rate is about 93.4% and 95.3% respectively. The adsorption rates of rare earth ions were above 80%, which indicated that the synthesized adsorbents had good hydrothermal stability, could be recycled, and the adsorption cost could be saved.
【學位授予單位】：南昌大學
【學位級別】：碩士
【學位授予年份】：2017
【分類號】：TB383.4;O647.3

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本文編號：2011892