石松科生物堿Palhinine A和Palhinine D全合成
發(fā)布時(shí)間:2018-06-12 09:23
本文選題:Palhinine + A。 參考:《有機(jī)化學(xué)》2017年06期
【摘要】:正J.Am.Chem.Soc.2017,139,4282~4285Palhinine型生物堿是一類以"異扭烷結(jié)構(gòu)"為特征的5/6/6/9四環(huán)體系或5/6/6/6/7五環(huán)體系石松科生物堿.從合成化學(xué)的角度來看,官能團(tuán)化異扭烷骨架的構(gòu)建及其含有兩個(gè)相鄰全碳季碳中心的氮雜九元環(huán)系的引入是該類生物
[Abstract]:The alkaloids of J.Am.Chem.Soc.2017 are a class of 5 / 6 / 6 / 9 four-ring systems or 5 / 6 / 6 / 6 / 6 / 7 pentacyclic alkaloids. From the point of view of synthetic chemistry, the construction of functional group heterosyncline skeleton and the introduction of aza-nine ring system containing two adjacent carbon quaternary carbon centers are these organisms.
【分類號】:O629.3
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本文編號:2009189
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