天津市冬季典型大氣重污染過(guò)程特征
本文選題:天津 + 冬季 ; 參考:《中國(guó)環(huán)境科學(xué)》2017年04期
【摘要】:基于污染物濃度、顆粒物化學(xué)組分及氣象參數(shù)等觀測(cè)數(shù)據(jù),綜合分析天津市2015年冬季典型重污染過(guò)程成因及污染特征,結(jié)果表明:天津市冬季重污染期間風(fēng)速0~4.0m/s,相對(duì)濕度80%以上,混合層高度僅為清潔天氣的1/3~1/2,靜穩(wěn)高濕的大氣環(huán)境對(duì)重污染影響較大.重污染過(guò)程N(yùn)O_2/SO_2比值較清潔天氣低,NO_3~-/SO_4~(2-)比值大于1,表明重污染期間天津市移動(dòng)源與固定源并重.重污染PM_(2.5)/PM_(10)比值較清潔天氣高,PM_1/PM_(2.5)比值較清潔天氣低,可能與重污染過(guò)程期間細(xì)粒子的吸濕增長(zhǎng)以及散煤燃燒排放有關(guān).污染初期NOR大于SOR,隨著重污染持續(xù),u6于受制于氨,SOR要高于NOR,需關(guān)注氣態(tài)前體物尤其是SO_2排放.OC與EC濃度高時(shí)二者相關(guān)性較低,SOC占OC的20%~54%,說(shuō)明冬季重污染期間散煤燃燒源和二次有機(jī)化學(xué)反應(yīng)對(duì)冬季重污染影響較大.
[Abstract]:Based on the observation data of pollutant concentration, particulate chemical composition and meteorological parameters, the causes and characteristics of typical heavy pollution process in 2015 winter in Tianjin were analyzed. The results show that during winter heavy pollution in Tianjin, the wind speed is 0 ~ 4.0 m / s, the relative humidity is more than 80%, the height of mixing layer is only 1 / 3 / 1 / 2 of that of clean weather, and the atmospheric environment with static stability and high humidity has a great influence on heavy pollution. The ratio of no _ 2 / so _ 2 in heavy pollution process is lower than that in clean weather. The ratio of no _ 2 / so _ 4 ~ (2-) is higher than 1, which indicates that the moving source and the fixed source in Tianjin are equal to each other during the heavy pollution period. The ratio of PM2.5 / PM10 in heavy pollution is higher than that in clean weather, and the ratio of PM2.5 / PM2.5 is lower than that in clean weather, which may be related to the increase of moisture absorption of fine particles and the emission from coal combustion during heavy pollution. In the initial stage of pollution, nor is greater than sor, and with the heavy pollution sustained by ammonia sor, it is higher than NOR. it is necessary to pay attention to gaseous precursors, especially when the concentration of SO2 and EC is high, and the correlation between them is lower than that of OC, indicating that the bulk coal is dispersed in winter during heavy pollution period, especially when the concentration of SO2 and EC is high. Combustion source and secondary organic chemical reaction have great influence on heavy pollution in winter.
【作者單位】: 天津市環(huán)境監(jiān)測(cè)中心;南開(kāi)大學(xué);天津市氣象科學(xué)研究所;
【基金】:國(guó)家重點(diǎn)研發(fā)計(jì)劃(2016YFC0208500) 國(guó)家科技支撐計(jì)劃(2014BAC23B00) 天津市重大科技專項(xiàng)(工程)項(xiàng)目(14ZCDGSF00027) 天津市科技計(jì)劃項(xiàng)目(15YFYSSF00030)
【分類號(hào)】:X51
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