本文關(guān)鍵詞：氮改性介孔碳的制備及其對(duì)水中壬基酚聚氧乙烯醚的吸附　出處：《石油學(xué)報(bào)(石油加工)》2017年03期 　論文類型：期刊論文

  更多相關(guān)文章： 介孔碳 氮改性介孔碳 吸附 壬基酚聚氧乙烯醚 循環(huán)再生

【摘要】：以軟模板法合成介孔碳(MC),添加三聚氰胺為改性劑合成氮改性介孔碳(NMC),并進(jìn)行N2吸-脫附、TEM和FT-IR表征,同時(shí)考察NMC和MC對(duì)水中壬基酚聚氧乙烯醚(NPEO10)的吸附性能。結(jié)果表明,NMC和MC的比表面積分別為579.6m~2/g和687.8m~2/g。吸附過(guò)程符合準(zhǔn)二級(jí)動(dòng)力學(xué)模型,吸附行為遵循Freundlich等溫模型,為優(yōu)惠吸附。吸附過(guò)程為可自發(fā)進(jìn)行的放熱反應(yīng),無(wú)化學(xué)鍵等強(qiáng)鍵作用,主要以物理吸附為主。吸附飽和后的NMC和MC經(jīng)5次循環(huán)/再生后對(duì)NPEO10的去除率均在60%以上。與活性炭(AC)相比,NMC和MC的吸附效果更優(yōu)越。
[Abstract]:Soft template synthesis of mesoporous carbon (MC), adding melamine as modifier of synthetic nitrogen modified mesoporous carbon (NMC), and N2 adsorption desorption, TEM and FT-IR characterization, the combined effect of NMC and MC on the water adsorption properties of nonylphenol ethoxylates (NPEO10). The results showed that NMC and MC the specific surface area were 579.6m~2/g and 687.8m~2/g. adsorption process conformed to the pseudo two order kinetics model, the adsorption behavior followed Freundlich isotherm model for preferential adsorption. The adsorption process was an exothermic reaction can occur spontaneously, without a strong chemical bond bond interaction, mainly by physical adsorption. After adsorption of NMC and MC after 5 cycles / regeneration after the removal rate of NPEO10 was more than 60%. Compared with the activated carbon (AC), NMC and MC adsorption effect is better.

【作者單位】： 中國(guó)石油大學(xué)化學(xué)工程學(xué)院;
【基金】：中國(guó)石油大學(xué)(華東)拔尖人才資助項(xiàng)目(RC2015011)資助
【分類號(hào)】：TQ424;X703
【正文快照】： 現(xiàn)代工業(yè)快速發(fā)展,產(chǎn)生了大量有機(jī)、無(wú)機(jī)有毒廢物,隨之這些工業(yè)廢物排放到環(huán)境中造成了嚴(yán)重的水、空氣和土壤污染。壬基酚聚氧乙烯醚(NPEO10)作為一種非離子表面活性劑,因其具有優(yōu)良的性能以及低廉的價(jià)格,廣泛應(yīng)用于家用洗滌劑、殺蟲劑以及工業(yè)產(chǎn)品中[1]。壬基酚聚氧乙烯醚物，

本文編號(hào)：1387707