本文選題：Cu-Ni-Al合金　切入點：人工海水　出處：《河南科技大學》2017年碩士論文

【摘要】：隨著我國“一帶一路”、“科技興�！钡戎卮髴�(zhàn)略工程的實施,對耐蝕銅合金的需求日益迫切。以海洋工程用耐蝕銅合金為例,年需求量約40萬噸,年產值約350億元。同時,復雜多變的海洋條件使得耐蝕銅合金的服役條件日益苛刻,關鍵部件的安全可靠性越來越高,對合金的耐蝕性能提出了更高要求。然而,目前研究和應用較多的傳統(tǒng)黃銅、B10、B30等耐蝕銅合金無法滿足高端領域使用要求。因此,在傳統(tǒng)Cu-Ni系耐蝕銅合金的基礎上,開展苛刻服役條件下新型高耐蝕銅合金的設計開發(fā)以及耐蝕機理研究,對于我國海洋工程用耐蝕銅合金的基礎理論研究和工程化應用具有重要意義。本文針對上述問題,在傳統(tǒng)Cu-Ni系耐蝕銅合金的基礎上,通過添加Al、Fe、Mn、RE等微合金化元素,制備了新型Cu-Ni-Al耐蝕銅合金;通過靜態(tài)人工海水全浸試驗,研究了海水浸泡時間對合金腐蝕速率和腐蝕形貌的影響規(guī)律,揭示了稀土添加量與耐蝕性能的內在關聯(lián);通過電化學測試手段,研究了海水浸泡時間與合金電化學阻抗譜等電化學性能的內在聯(lián)系,探索了稀土添加量對合金電化學行為的影響規(guī)律;通過海水沖刷試驗,研究了沖刷速度和時間對合金腐蝕速率和腐蝕形貌的影響規(guī)律,揭示了稀土對合金沖刷腐蝕行為的作用機制。研究結論如下:1.浸泡條件下,Cu-Ni-Al合金和添加0.014%RE、0.035%RE的Cu-Ni-Al合金的腐蝕速率變化規(guī)律均為:初期腐蝕速率較大,隨浸泡時間延長,合金表面鈍化膜開始形成并逐漸完善,合金腐蝕速率降低并趨于平穩(wěn);在浸泡條件下,隨著稀土的添加,合金耐腐蝕性能提高,腐蝕速率降低,168 h時添加0.014%RE、0.035%RE的Cu-Ni-Al合金腐蝕速率分別比Cu-Ni-Al合金降低26%和29%,添加0.035%RE的Cu-Ni-Al合金耐腐蝕性最好。2.浸泡條件下,Cu-Ni-Al合金和添加0.014%RE、0.035%RE的Cu-Ni-Al合金的電化學行為變化規(guī)律相同,在浸泡初期,12 h時電化學阻抗譜中開始出現(xiàn)容抗弧,此時合金表面已經開始形成鈍化膜,隨浸泡時間延長,容抗弧半徑增大,三種合金均在168 h時達到穩(wěn)定,合金表面鈍化膜處于溶解與生成的動態(tài)平衡之中;在浸泡條件下,隨著稀土的添加,合金自腐蝕電位提高,腐蝕電流密度降低,添加0.035%RE的Cu-Ni-Al合金自腐蝕電流密度最低為2.179×10-6 A·cm-2,比Cu-Ni-Al合金和添加0.014%RE的Cu-Ni-Al合金分別降低24.2%和24.1%。3.在流動海水中,相同流速下Cu-Ni-Al合金和添加0.014%RE、0.035%RE的Cu-Ni-Al合金的腐蝕速率變化規(guī)律均為:初期腐蝕速率較高,隨沖刷時間延長,合金腐蝕速率降低并趨于穩(wěn)定,合金表面鈍化膜隨時間延長逐漸完善,性能提高;不同流速下Cu-Ni-Al合金和添加0.014%RE、0.035%RE的Cu-Ni-Al合金的腐蝕速率變化規(guī)律有所差異,1.5 m/s條件下初期12 h到24 h時合金腐蝕速率降低較快,合金表面鈍化膜形成后較為穩(wěn)定不易受到破壞;24 h到96 h期間隨著流速增大,合金腐蝕速率升高,合金表面鈍化膜易受到海水沖擊作用而破壞;96 h后合金腐蝕速率趨于穩(wěn)定,合金表面鈍化膜已經達到穩(wěn)定狀態(tài)。4.在流動海水中,隨著稀土添加,合金耐腐蝕性能提高,在1.5 m/s和3.0m/s流速下,合金腐蝕速率相差不大,但添加稀土的合金鈍化膜性能較好,合金腐蝕速率降低較快;在5.0 m/s流速下合金初期腐蝕速率差異較小,隨時間延長,添加稀土的合金腐蝕速率較低,合金鈍化膜性能更優(yōu),耐蝕性能提高,添加0.035%RE的Cu-Ni-Al合金腐蝕速率為0.1488 g·m-2·h-1,腐蝕速率比Cu-Ni-Al合金降低43%。
[Abstract]:Along with our country "The Belt and Road", "the implementation of major strategic project technology and the sea", on the corrosion resistance of copper alloy. With the increasingly urgent demand for marine engineering alloy as an example, the annual demand of about 400 thousand tons, the annual output value of about 35 billion yuan. At the same time, the complex sea conditions make the service condition to corrosion the copper alloy has been harsh, safety and reliability of key parts of more and more high, put forward higher requirements on the corrosion resistance of alloys. However, more research and application of traditional brass, B10, B30 alloy can not meet the high-end use requirements. Therefore, based on the traditional Cu-Ni system on corrosion resistance of copper alloy to carry out the design and development of new service demanding, high corrosion resistance and corrosion resistance of copper alloy under the condition of mechanism research for corrosion resistance of copper alloy based on theoretical research and engineering application significance of Ocean Engineering in China. In this paper. The problem, based on the traditional Cu-Ni system on corrosion resistance of copper alloy, with the addition of Al, Fe, Mn, RE and other micro alloying elements, the new Cu-Ni-Al alloy was prepared by static; artificial seawater immersion test, the influence law of the alloy corrosion rate and morphology of the seawater immersion time was studied, revealing internal connection and corrosion resistance of rare earth content; by means of electrochemical testing, analyzing the relation between seawater immersion time and alloy electrochemical impedance spectroscopy electrochemical performance, explores the influence of the addition of rare earth alloys on the electrochemical behavior of the law; through sea water scouring, influence on the alloy corrosion rate and corrosion morphology and scouring velocity time study, reveal the mechanism of rare earth on erosion corrosion behavior of the alloy. The research conclusions are as follows: 1. soaking condition, Cu-Ni-Al alloy and Cu-Ni-Al alloy added 0.014%RE, 0.035%RE The corrosion rate changes are: the initial corrosion rate is high, with the increase of immersion time, the alloy surface passivation film began to form and gradually improve, corrosion rate of the alloy decreases and tends to be stable; in immersion conditions, with the addition of rare earth alloy, and improve corrosion resistance, the corrosion rate decreased, adding 0.014%RE 168 h, Cu-Ni-Al alloy the corrosion rate of 0.035%RE were 29% and 26% lower than that of Cu-Ni-Al alloy, corrosion resistance of Cu-Ni-Al alloy.2. the best soaking conditions of adding 0.035%RE, Cu-Ni-Al and 0.014%RE alloy added, the electrochemical behavior changes of Cu-Ni-Al alloy 0.035%RE the same, at the initial stage of immersion, electrochemical impedance spectroscopy of 12 h began to appear in the capacitive arcs, this alloy surface has been to form a passive film, with the increase of immersion time, increasing the capacitance arc radius of three alloys, reached the stable at 168 h, the alloy surface passivation film in solution With the dynamic balance of generation; in immersion conditions, with the addition of rare earth alloy, corrosion potential, corrosion current density decreased, the addition of 0.035%RE Cu-Ni-Al alloy, the corrosion current density for a minimum of 2.179 * 10-6 A, cm-2, and 24.1%.3. decreased by 24.2% in flowing seawater respectively than that of Cu-Ni-Al alloy and Cu-Ni-Al alloy added 0.014%RE Cu-Ni-Al, the same flow rate and the addition of 0.014%RE alloy, the corrosion rate of change of Cu-Ni-Al alloy 0.035%RE are: the initial corrosion rate is high, with scouring time, corrosion rate of the alloy decreased and stabilized, the passivation film on the surface of alloy gradually perfect, improve the performance of Cu-Ni-Al alloy under different velocity; and adding 0.014%RE, corrosion the rate of change of Cu-Ni-Al alloy 0.035%RE the difference under the condition of 1.5 m/s at the beginning of 12 h to 24 h alloy corrosion rate decreased rapidly, alloy The surface passivation film after the formation of a more stable are not easy to be damaged; 24 h to 96 h during the period with increased velocity increases and the corrosion rate of the alloy, alloy surface passivation membrane is susceptible to water impact damage; after 96 h alloy corrosion rate tends to be stable, the alloy surface passivation film has reached a steady state in flowing seawater with.4.. Addition of rare earth alloy, the corrosion resistance is improved, at 1.5 m/s and the 3.0m/s flow rate, corrosion rate of the alloy are similar, but the addition of rare earth alloy passivation performance good, corrosion rate of the alloy decreases quickly; at a flow rate of 5 m/s alloy at the initial corrosion rate difference is small, with time prolonging, the corrosion rate of the alloy of rare earth is low. The performance of passive film alloy has better corrosion resistance, the corrosion rate of Cu-Ni-Al alloy increase, adding 0.035%RE 0.1488 G - m-2 - H-1, the corrosion rate of 43%. lower than that of Cu-Ni-Al alloy

【學位授予單位】：河南科技大學
【學位級別】：碩士
【學位授予年份】：2017
【分類號】：TG172.5

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