改善ZrCo儲(chǔ)氚合金抗歧化性能的研究綜述:晶體結(jié)構(gòu)、放氫熱力學(xué)和歧化動(dòng)力學(xué)
發(fā)布時(shí)間:2018-03-24 05:22
本文選題:ZrCo 切入點(diǎn):儲(chǔ)氚合金 出處:《材料導(dǎo)報(bào)》2017年21期
【摘要】:ZrCo合金由于優(yōu)異的儲(chǔ)氫性能以及安全特性,已被國(guó)際熱核實(shí)驗(yàn)堆(ITER)研發(fā)團(tuán)隊(duì)選取為用于氫同位素快速儲(chǔ)存與供給的重點(diǎn)備選材料。然而,由吸/放氫循環(huán)過(guò)程中發(fā)生的氫致歧化效應(yīng)導(dǎo)致的儲(chǔ)氫性能嚴(yán)重衰減,成為了ZrCo合金推廣應(yīng)用于氫同位素快速儲(chǔ)存與供給的最大障礙。因此,改善ZrCo合金的抗氫致歧化性能對(duì)其廣泛應(yīng)用于氫同位素快速儲(chǔ)存與供給領(lǐng)域具有重要意義。本文介紹了ZrCo合金的儲(chǔ)氫性能和氫致歧化特性,綜述了元素替代(摻雜元素部分替代Zr或Co)改善ZrCo合金抗歧化性能的研究進(jìn)展,并指出進(jìn)一步改善ZrCo合金抗歧化性能的必要性及可能的發(fā)展方向。
[Abstract]:Due to its excellent hydrogen storage and safety properties, ZrCo alloy has been selected as a key candidate for rapid storage and supply of hydrogen isotopes by the research and development team of the International Thermonuclear Experimental reactor. The serious attenuation of hydrogen storage performance due to the hydrogen-induced disproportionation during the hydrogen absorption / desorption cycle has become the biggest obstacle for the rapid storage and supply of hydrogen isotopes in ZrCo alloys. It is of great significance to improve the hydrogen resistance of ZrCo alloy for its wide application in the field of rapid storage and supply of hydrogen isotopes. This paper introduces the hydrogen storage properties and hydrogen disproportionation properties of ZrCo alloys. In this paper, the research progress of element substitution (doping element partially replacing Zr or Co) to improve the antidisproportionation performance of ZrCo alloy is reviewed, and the necessity and the possible development direction of further improving the antidisproportionation property of ZrCo alloy are pointed out.
【作者單位】: 表面物理與化學(xué)重點(diǎn)實(shí)驗(yàn)室;中國(guó)工程物理研究院材料研究所;
【基金】:國(guó)家自然科學(xué)基金(21573200;21601165) 國(guó)家科技部磁約束聚變專項(xiàng)(2011GB111003) 中國(guó)工程物理研究院科學(xué)技術(shù)發(fā)展基金(2015B0302067)
【分類號(hào)】:TG139.7
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