本文選題：氧化銅 + 水熱法�。� 參考：《人工晶體學(xué)報(bào)》2017年08期

【摘要】：以NaOH、尿素為沉淀劑,Cu(NO_3)_2·3H_2O為銅源,采用水熱法控制合成了一種紡錘狀CuO微結(jié)構(gòu)。采用XRD、SEM、TEM和HRTEM等手段對(duì)產(chǎn)物進(jìn)行了表征和分析,結(jié)果表明該CuO呈單斜晶相且具有很高的結(jié)晶性。研究了反應(yīng)體系p H值、尿素濃度、反應(yīng)溫度、反應(yīng)時(shí)間等因素對(duì)CuO形貌的影響,結(jié)果表明改變NaOH與尿素的相對(duì)濃度能顯著調(diào)變CuO的形貌,使其呈現(xiàn)出空心微球、花狀以及紡錘狀等結(jié)構(gòu)。提出了紡錘狀CuO微結(jié)構(gòu)可能的生長(zhǎng)機(jī)理。
[Abstract]:Using NaOH and urea as precipitant Cu (no _ 3) _ 2H _ 2O as copper source, a spindle-like CuO microstructure was synthesized by hydrothermal method. The products were characterized and analyzed by means of XRDX SEM TEM and HRTEM. The results show that the CuO is monoclinic and has high crystallinity. The effects of reaction system pH value, urea concentration, reaction temperature and reaction time on the morphology of CuO were studied. The results showed that the morphology of CuO could be changed significantly by changing the relative concentration of NaOH and urea. Flowers and spindles, etc. The possible growth mechanism of spindle-like CuO microstructures was proposed.
【作者單位】： 遵義師范學(xué)院化學(xué)化工學(xué)院;中國(guó)科學(xué)院山西煤炭化學(xué)研究所煤轉(zhuǎn)化國(guó)家重點(diǎn)實(shí)驗(yàn)室;
【基金】：貴州省科技廳項(xiàng)目(QKHJZ[2015]2145,QKHJC[2017]1208) 貴州省教育廳項(xiàng)目(QJHKYZ[2015]394,QJHKYZ[2016]093)
【分類號(hào)】：TQ131.21

【相似文獻(xiàn)】

相關(guān)期刊論文 前2條

1 賀會(huì)蘭,鄭學(xué)忠,魏雨;強(qiáng)迫水解法制備紡錘狀α-Fe_2O_3的研究[J];河北師范大學(xué)學(xué)報(bào);1997年03期

2 魏雨,邵素霞,鹿平,史永宏;紡錘狀α－Fe_2O_3微粒內(nèi)部結(jié)構(gòu)的TEM分析[J];電子顯微學(xué)報(bào);1996年06期

，

本文編號(hào)：2102455