Two isomeric metal-organic frameworks（MOFs） with 2-dimensional（2D） and 3-dimensional（3D） topologies both comprised of Cu（Ⅱ） and OTf（OTf = trifluoromethanesulfonate） ions were synthesized and characterized.The CO₂,CH₄ and N₂ adsorption properties of the two isomeric MOFs were investigated from 263 K to 298 K at0.1 MPa.The results showed that the 2D MOF exhibited a higher selectivity for CO₂ from CO₂/CH₄ and CH₄from CH

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期刊論文
[1]Separation of CO2/CH4 and CH4/N2 mixtures using MOF-5 and Cu3（BTC）2[J]. Junmin Li,Jiangfeng Yang,Libo Li,Jinping Li.  Journal of Energy Chemistry. 2014(04)



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