【摘要】：由于高分子具有尺寸長(zhǎng)短不一、柔性等特點(diǎn),很難通過(guò)普通方法合成具有結(jié)晶性和多孔性的高分子材料。而高分子金屬配合物材料不僅繼承了高分子材料的傳統(tǒng)性質(zhì),同時(shí)也可以獲得配合物的優(yōu)點(diǎn),比如高結(jié)晶性和多孔性。本文系統(tǒng)總結(jié)了合成結(jié)晶性的多孔高分子配合物材料的方法,包括光誘導(dǎo)聚合法、配位自主裝法、分步合成法以及后修飾法。同時(shí)介紹了它們的表征方法以及潛在應(yīng)用領(lǐng)域,并討論了該領(lǐng)域研究中存在的各種機(jī)遇與挑戰(zhàn)。
[Abstract]:It is difficult to synthesize crystalline and porous polymer materials by ordinary method because of their different size and flexibility. The polymer metal complex material not only inherits the traditional properties of the polymer material, but also can obtain the advantages of the complex, such as high crystallinity and porosity. In this paper, the synthesis methods of crystalline porous polymer complexes are summarized systematically, including photoinduced polymerization, coordination self-loading, step-by-step synthesis and post-modification. At the same time, their characterization methods and potential application fields are introduced, and the opportunities and challenges existing in this field are also discussed.
【作者單位】： 南開(kāi)大學(xué)化學(xué)學(xué)院;藥物化學(xué)生物學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室南開(kāi)大學(xué);南開(kāi)大學(xué)藥學(xué)院;
【基金】：the China Young 1000 Talents program NSFC (Grant No.21601093)~~
【分類號(hào)】：O641.4

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