【摘要】：碳龍配合物是一類嶄新的金屬雜芳香化合物,具有新穎的結(jié)構(gòu)和獨(dú)特的性能,有著很好的潛在應(yīng)用前景.然而,已報(bào)道的碳龍配合物絕大部分不帶有可進(jìn)一步化學(xué)修飾的有機(jī)官能團(tuán).此狀況阻礙了其進(jìn)一步化學(xué)修飾和實(shí)現(xiàn)功能材料化的應(yīng)用研究.烯烴基團(tuán)是一類高活性有機(jī)官能團(tuán)——可發(fā)生高轉(zhuǎn)化率的聚合反應(yīng)、點(diǎn)擊反應(yīng)等多種有機(jī)反應(yīng).為此,合成烯基化的碳龍配合物,可實(shí)現(xiàn)這類新穎分子的有機(jī)功能團(tuán)化,對(duì)其后續(xù)實(shí)際應(yīng)用有著重要的意義和價(jià)值.利用鋨雜戊搭炔的反應(yīng)性以及合成底物的修飾,設(shè)計(jì)合成了一系列烯基化的碳龍配合物,并對(duì)其進(jìn)行了系統(tǒng)表征.
[Abstract]:Carbon dragon complex is a new class of metal hetero-aromatic compounds with novel structure and unique properties, and has a good potential application prospect. However, most of the reported carbon dragon complexes do not contain further chemically modified organic functional groups. This situation hinders the further chemical modification and the application of functional materials. Olefin group is a kind of highly active organic functional group-many kinds of organic reactions, such as high conversion polymerization, click reaction and so on. Therefore, the synthesis of alkylated carbon dragon complexes can realize the organic functional grouping of these novel molecules, which is of great significance and value for its subsequent practical application. A series of alkenated carbon dragon complexes were designed and synthesized by using the reactivity of osmium heteropentynes and modification of synthetic substrates, and their systematic characterization was carried out.
【作者單位】： 廈門大學(xué)化學(xué)化工學(xué)院;廈門大學(xué)材料學(xué)院;
【基金】：國家自然科學(xué)基金(Nos.21490573,21332002,21472156)資助項(xiàng)目~~
【分類號(hào)】：O641.4
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本文編號(hào)：2450711