【摘要】：金屬鹵化物MCl2(M=Pb~(2+),Cd~(2+),Co~(2+))分別與苯并噻唑(btz)在濃鹽酸中、80℃下反應,合成了3種有機-無機雜化化合物:(btzH)[(PbCl_3)](1),(btzH)_2[CdCl_4]·2H_2O(2)和(btzH)2[CoCl_4]·2H_2O(3),其中化合物2和3結構相似。對化合物1~3進行了粉末衍射、紅外和紫外光譜、元素分析、熱重分析以及X射線單晶衍射表征。熒光測試發(fā)現(xiàn):化合物1~3在393nm處有發(fā)射峰,該熒光來源于苯并噻唑環(huán)中電子的π…π躍遷。
[Abstract]:Three organic-inorganic hybrid compounds,: (btzH) [(PbCl_3)] (1), were synthesized by the reaction of metal halide MCl2 (MxPb2), Cd~ (2), Co~ (2) with benzothiazole (btz) in concentrated hydrochloric acid at 80 鈩，

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