銅促進硫代色酮類化合物的合成研究
發(fā)布時間:2018-12-11 09:32
【摘要】:基于底物設(shè)計的概念,建立了一種以β-羰基二硫代羧酸酯和取代鄰溴代苯乙酮為合成子,在碘化亞銅/鄰菲羅啉促進下高化學(xué)選擇性地合成硫代色酮類衍生物的新方法.該方法高效、簡便且收率高.
[Abstract]:Based on the concept of substrate design, a new method for the highly chemically selective synthesis of thiochroone derivatives with 尾 -carbonyl dithiocarboxylate and substituted o-bromoacetophenone as synthesizers promoted by cuprous iodide / o-phenanthroline was established. The method is efficient, simple and high yield.
【作者單位】: 青島科技大學(xué)化學(xué)與分子工程學(xué)院生態(tài)化工國家重點實驗室培育基地;
【基金】:國家自然科學(xué)基金(Nos.21572110,21372137) 山東省自然科學(xué)基金(No.ZR2014BM006)資助項目~~
【分類號】:O621.3;TQ460.1
,
本文編號:2372311
[Abstract]:Based on the concept of substrate design, a new method for the highly chemically selective synthesis of thiochroone derivatives with 尾 -carbonyl dithiocarboxylate and substituted o-bromoacetophenone as synthesizers promoted by cuprous iodide / o-phenanthroline was established. The method is efficient, simple and high yield.
【作者單位】: 青島科技大學(xué)化學(xué)與分子工程學(xué)院生態(tài)化工國家重點實驗室培育基地;
【基金】:國家自然科學(xué)基金(Nos.21572110,21372137) 山東省自然科學(xué)基金(No.ZR2014BM006)資助項目~~
【分類號】:O621.3;TQ460.1
,
本文編號:2372311
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