【摘要】：生物質(zhì)指由綠色植物直接或間接利用太陽(yáng)能進(jìn)行光合作用而形成的有機(jī)物質(zhì),是一種重要的可再生資源。由于世界范圍的能源危機(jī)以及相關(guān)的環(huán)境污染日益加重,木質(zhì)生物質(zhì)能源的可再生性和環(huán)境友好性引起了人們的廣泛關(guān)注。生物質(zhì)能通過(guò)加氫裂解、熱解、氣化、液化以及直接燃燒等方式轉(zhuǎn)化為能源。木質(zhì)生物質(zhì)通�？稍诟邷叵逻M(jìn)行催化加氫,得到含苯環(huán)的小分子物質(zhì),可用于化學(xué)品、石油類(lèi)產(chǎn)品等的制備。而熱解生物質(zhì)產(chǎn)生生物油是生物質(zhì)能源轉(zhuǎn)化的另一種方式,得到的副產(chǎn)物生物炭是一種具有多孔結(jié)構(gòu)的堅(jiān)固的碳框架,常被用以進(jìn)行土壤修復(fù)以及碳封存。但是其對(duì)于土壤性質(zhì)及土壤生物的影響一直存在爭(zhēng)議,近年來(lái),許多研究關(guān)注生物炭材料的其它應(yīng)用。例如將生物炭進(jìn)行修飾改性后,可用于有機(jī)污染物和重金屬吸附；而將生物炭作為基底材料負(fù)載金屬納米顆粒,則可用于催化有機(jī)物轉(zhuǎn)化等。本文主要研究利用快速熱解方式制備負(fù)載金屬的催化劑,并且研究其在木質(zhì)素加氫反應(yīng)中的催化作用。此外,我們研究了將不同來(lái)源的生物炭應(yīng)用于土壤修復(fù)時(shí)可能發(fā)生的生物毒性影響,主要的研究?jī)?nèi)容及結(jié)論如下：1.利用快速熱解裝置一步熱解浸漬鎳鹽和鉬鹽的鋸末,得到負(fù)載納米金屬鎳和碳化鉬的生物炭催化劑Ni-Mo2C/C。將其應(yīng)用于木質(zhì)素加氫催化,得到的液體產(chǎn)物通過(guò)GC-MS分析產(chǎn)物類(lèi)型及產(chǎn)率,結(jié)果表明添加催化劑反應(yīng)組中,產(chǎn)物相比對(duì)照組明顯增多且選擇性增加。2.利用傳統(tǒng)化學(xué)還原法將鎳鹽和鉬鹽還原于同樣條件制備的生物炭上,得到催化劑材料(Ni-MoO2/C)應(yīng)用于木質(zhì)素加氫催化,并沒(méi)有得到與Ni-Mo2C/C類(lèi)似的良好效果,證明一步熱解方法具有顯著的優(yōu)越性。結(jié)合TEM, XRD, XPS等表征以及GC-MS產(chǎn)物分布推測(cè)可能的反應(yīng)機(jī)理,納米鎳和碳化鉬顆粒能有效進(jìn)攻碳氧雙鍵,且石墨化的碳基底結(jié)構(gòu)能幫助催化劑上電子轉(zhuǎn)移。3.利用不同生物質(zhì)材料(稻殼、鋸末、蒲草)在相同條件下通過(guò)快速熱解得到生物炭材料,并且研究其提取液對(duì)于植物(小麥)、動(dòng)物(秀麗桿隱線蟲(chóng))、微生物(銅綠假單胞菌)的生長(zhǎng)影響。結(jié)果表明,稻殼、鋸末類(lèi)生物炭浸出液對(duì)生物生長(zhǎng)影響較小,而蒲草類(lèi)生物質(zhì)浸出液嚴(yán)重抑制生物生長(zhǎng),特別是對(duì)秀麗桿隱線蟲(chóng)具有劇烈毒性。
[Abstract]:Biomass, which is an important renewable resource, refers to the organic matter formed by the direct or indirect use of solar energy for photosynthesis by green plants. Due to the worldwide energy crisis and the increasing environmental pollution, the regeneration and environmental friendliness of wood biomass energy have attracted wide attention. Biomass energy is converted into energy by hydrocracking, pyrolysis, gasification, liquefaction and direct combustion. Wood biomass can be hydrogenated at high temperature to obtain small molecular substances containing benzene ring, which can be used in the preparation of chemicals, petroleum products and so on. Pyrolysis biomass to produce bio-oil is another way of biomass energy conversion. The by-product biochar is a porous structure of a solid carbon framework, often used for soil remediation and carbon sequestration. However, its influence on soil properties and soil organisms has been controversial. In recent years, many researches have focused on other applications of biochar materials. For example, modified biochar can be used to adsorb organic pollutants and heavy metals, while biochar can be used as substrate material to support metal nanoparticles, which can be used to catalyze organic conversion and so on. In this paper, the catalyst supported on metal was prepared by rapid pyrolysis, and its catalytic effect in hydrogenation of lignin was studied. In addition, we studied the possible toxic effects of biochar from different sources on soil remediation. The main contents and conclusions are as follows: 1. Using a rapid pyrolysis device, the sawdust of nickel salt and molybdenum salt was pyrolyzed in one step, and the biocarbon catalyst Ni-Mo2C/C. supported on nano-nickel and molybdenum carbide was obtained. The liquid product was analyzed by GC-MS for the type and yield of lignin hydrogenation. The results showed that the products in the reaction group increased significantly and selectivity was increased compared with the control group. The nickel salt and molybdenum salt were reduced to biochar under the same conditions by the traditional chemical reduction method. The catalyst material (Ni-MoO2/C) was applied to the hydrogenation of lignin, and the effect was not similar to that of Ni-Mo2C/C. It is proved that the one-step pyrolysis method has obvious advantages. Combined with the TEM, XRD, XPS characterization and the possible reaction mechanism of GC-MS products distribution, the nickel and molybdenum carbide nanoparticles can effectively attack the carbon-oxygen double bond, and the graphitized carbon substrate structure can help the electron transfer on the catalyst. Using different biomass materials (rice husk, sawdust, cattlegrass) under the same conditions, the biochar materials were obtained by rapid pyrolysis, and the extracts of biochar were studied for plants (wheat) and animals (Cryptonematodes elegans). Effects of microorganisms (Pseudomonas aeruginosa) on growth. The results showed that rice husks and sawdust biochar leachate had little effect on biological growth, while the biomass extract of Cattlegrass seriously inhibited biological growth, especially to Cryptonematodes elegans.
【學(xué)位授予單位】：中國(guó)科學(xué)技術(shù)大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2016
【分類(lèi)號(hào)】：O643.36

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