吩嗪衍生物在分子識別與自組裝中的應(yīng)用進展
發(fā)布時間：2018-11-11 13:57
【摘要】：種類繁多的吩嗪類化合物對有機化學(xué)研究者來說并不陌生,它廣泛地存在于有機天然產(chǎn)物中并且具有較好的生物活性,含有天然骨架的吩嗪類化合物的合成過程簡單,分子結(jié)構(gòu)的功能化容易.該類化合物具有多個配位點和較大的共軛體系,使其容易形成氫鍵、離子鍵以及π-π堆積作用等弱相互作用.因此,吩嗪類化合物在超分子化學(xué)中的應(yīng)用極為廣泛.分子識別(MR)和超分子自組裝(MS-A)是一直以來是超分子化學(xué)的兩大重要的研究方向,綜述了近幾年來吩嗪衍生物在MR和MS-A中的應(yīng)用進展.根據(jù)與吩嗪衍生物所作用的客體的類型的不同將MR分為陽離子識別(CR)、陰離子識別(AR)以及中性分子識別(NMR)三類.根據(jù)誘導(dǎo)因素的不同又將MS-A分為以下五類:氫鍵作用誘導(dǎo)的自組裝(HBSA)、堆積作用誘導(dǎo)的自組裝(ASA)、金屬-配體作用誘導(dǎo)的自組裝(M-LSA)、多種作用力協(xié)同作用誘導(dǎo)的自組裝(MFSA)以及外界環(huán)境的導(dǎo)向作用誘導(dǎo)的自組裝(OESA).
[Abstract]:Many kinds of phenazine compounds are not unfamiliar to organic chemistry researchers. They widely exist in organic natural products and have good biological activity. The synthesis process of phenazine compounds containing natural skeleton is simple. It is easy to functionalize the molecular structure. These compounds have many coordination points and large conjugated systems, which make them easy to form hydrogen bonds, ionic bonds and 蟺-蟺 stacking interactions. Therefore, phenazine compounds are widely used in supramolecular chemistry. Molecular recognition (MR) and supramolecular self-assembly (MS-A) are two important research directions in supramolecular chemistry. The applications of phenazine derivatives in MR and MS-A in recent years are reviewed. MR is classified into cationic (CR), anion recognition (AR) and neutral molecular recognition (NMR) according to the different types of guest interacting with phenazine derivatives. According to the different inducing factors, MS-A can be divided into the following five categories: Self-assembled (HBSA), piling induced by hydrogen bonding, self-assembled (ASA), metal-ligand interaction induced self-assembly (M-LSA). Self-assembled (MFSA) induced by synergistic action of multiple forces and self-assembled (OESA). Induced by guidance of external environment
【作者單位】： 西北師范大學(xué)化學(xué)化工學(xué)院生態(tài)環(huán)境相關(guān)高分子材料教育部重點實驗室甘肅省高分子材料重點實驗室;
【基金】：國家自然科學(xué)基金(Nos.21662031,21661018,21574104,21262032)資助項目~~
【分類號】：O641.3
[Abstract]:Many kinds of phenazine compounds are not unfamiliar to organic chemistry researchers. They widely exist in organic natural products and have good biological activity. The synthesis process of phenazine compounds containing natural skeleton is simple. It is easy to functionalize the molecular structure. These compounds have many coordination points and large conjugated systems, which make them easy to form hydrogen bonds, ionic bonds and 蟺-蟺 stacking interactions. Therefore, phenazine compounds are widely used in supramolecular chemistry. Molecular recognition (MR) and supramolecular self-assembly (MS-A) are two important research directions in supramolecular chemistry. The applications of phenazine derivatives in MR and MS-A in recent years are reviewed. MR is classified into cationic (CR), anion recognition (AR) and neutral molecular recognition (NMR) according to the different types of guest interacting with phenazine derivatives. According to the different inducing factors, MS-A can be divided into the following five categories: Self-assembled (HBSA), piling induced by hydrogen bonding, self-assembled (ASA), metal-ligand interaction induced self-assembly (M-LSA). Self-assembled (MFSA) induced by synergistic action of multiple forces and self-assembled (OESA). Induced by guidance of external environment
【作者單位】： 西北師范大學(xué)化學(xué)化工學(xué)院生態(tài)環(huán)境相關(guān)高分子材料教育部重點實驗室甘肅省高分子材料重點實驗室;
【基金】：國家自然科學(xué)基金(Nos.21662031,21661018,21574104,21262032)資助項目~~
【分類號】：O641.3
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