棕櫚酸異丙酯反應體系熱力學參數(shù)的測定
發(fā)布時間:2018-05-06 20:14
本文選題:棕櫚酸異丙酯 + 熱力學; 參考:《高;瘜W工程學報》2017年03期
【摘要】:為確定"兩步法"合成棕櫚酸異丙酯工藝過程熱力學可行性,進一步提高工程應用中引用數(shù)據(jù)的可靠性,采用DSC-60差示掃描量熱儀和XRY-1C氧彈量熱器等分別對該反應體系中物質(zhì)的定壓比熱容和燃燒熱進行了實驗測定,并通過熱力學關系式計算得到有關物質(zhì)的摩爾生成焓及反應焓變,為連續(xù)化工藝的設計提供了基礎熱力學數(shù)據(jù)。
[Abstract]:In order to determine the thermodynamic feasibility of the "two-step" process for the synthesis of isopropyl palmitate, the reliability of the cited data in engineering application is further improved. DSC-60 differential scanning calorimeter and XRY-1C oxygen bomb calorimeter were used to measure the specific heat capacity and combustion heat of the reaction system respectively. The molar enthalpy of formation and the enthalpy of reaction were calculated by thermodynamics. The basic thermodynamic data are provided for the design of continuous process.
【作者單位】: 鄭州大學化工與能源學院;河南省產(chǎn)品質(zhì)量監(jiān)督檢驗院;
【分類號】:O642
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,本文編號:1853715
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