本文選題：金屬-有機(jī)骨架 + UiO系列��； 參考：《無(wú)機(jī)化學(xué)學(xué)報(bào)》2017年05期

【摘要】：本文綜述了包括UiO-66、UiO-67和UiO-68在內(nèi)的UiO系列金屬-有機(jī)骨架(MOFs)材料的合成方法、結(jié)構(gòu)特點(diǎn)及各類(lèi)應(yīng)用。系統(tǒng)介紹了利用包括擴(kuò)散法、溶劑熱法、微波輔助法、機(jī)械研磨法、持續(xù)流合成法及電化學(xué)合成法等方法合成UiO系列MOFs材料的反應(yīng)條件、產(chǎn)物特征及優(yōu)缺點(diǎn)。UiO系列MOFs因穩(wěn)定的Zr-O鍵及超高的配位數(shù)而具有超高熱穩(wěn)定性和化學(xué)穩(wěn)定性等,其在化學(xué)催化、光催化、氣體吸附、氣體分離、液相吸附有機(jī)污染物、熒光、傳感、醫(yī)學(xué)和電容器等方面均具有十分廣泛的應(yīng)用。同時(shí),本文還根據(jù)UiO系列MOFs材料的研究現(xiàn)狀對(duì)其未來(lái)發(fā)展趨勢(shì)進(jìn)行了展望。
[Abstract]:In this paper, the synthetic methods, structural characteristics and various applications of UiO series of metal-organic framework MOFs, including UiO-66, UiO-67 and UiO-68, are reviewed.The reaction conditions for the synthesis of UiO series MOFs materials by means of diffusion method, solvothermal method, microwave assisted method, mechanical grinding method, continuous flow synthesis method and electrochemical synthesis method are introduced systematically.Product characteristics and advantages and disadvantages. UiO series MOFs has high thermal stability and chemical stability due to its stable Zr-O bond and high coordination number. It is widely used in chemical catalysis, photocatalysis, gas adsorption, gas separation, liquid phase adsorption of organic pollutants, fluorescence, etc.Sensing, medicine and capacitors are widely used.At the same time, according to the research status of UiO series MOFs materials, the future development trend is prospected.
【作者單位】： 北京建筑大學(xué)建筑結(jié)構(gòu)與環(huán)境修復(fù)功能材料北京市重點(diǎn)實(shí)驗(yàn)室;北京建筑大學(xué)城市雨水系統(tǒng)與水環(huán)境教育部重點(diǎn)實(shí)驗(yàn)室;
【基金】：國(guó)家自然科學(xué)基金(No.51578034) 北京自然科學(xué)基金重點(diǎn)項(xiàng)目B類(lèi)(No.KZ201410016018) 北京百千萬(wàn)人才工程培養(yǎng)經(jīng)費(fèi)(No.2016023)資助項(xiàng)目
【分類(lèi)號(hào)】：O641.4;TB383
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本文編號(hào)：1734057