本文選題：聚合誘導(dǎo)自組裝　切入點(diǎn)：可逆加成-斷裂鏈轉(zhuǎn)移聚合(RAFT)聚合　出處：《有機(jī)化學(xué)》2017年08期 　論文類型：期刊論文

【摘要】：聚合誘導(dǎo)自組裝是一種基于活性聚合的新型自組裝策略,其特點(diǎn)是可以在較高固含量體系中一步制備不同形貌的聚集體結(jié)構(gòu).利用可逆加成-斷裂鏈轉(zhuǎn)移聚合(RAFT)活性聚合,在乙醇溶液中合成新型P4VP-b-PBz MA嵌段共聚物,發(fā)現(xiàn)聚合誘導(dǎo)自組裝過(guò)程中聚集體結(jié)構(gòu)發(fā)生球→蠕蟲→囊泡的連續(xù)轉(zhuǎn)變.親溶劑鏈段P4VP的變化可有效調(diào)控聚集體的結(jié)構(gòu)和尺寸.此外,采用無(wú)規(guī)共聚方法,研究了P4VP-b-(PHPMA-co-PBz MA)三嵌段共聚物在聚合誘導(dǎo)自組裝過(guò)程中組裝體結(jié)構(gòu)的轉(zhuǎn)變過(guò)程.
[Abstract]:Polymerization-induced self-assembly is a novel self-assembly strategy based on active polymerization, which can be used to prepare aggregates with different morphologies in a higher solid content system in one step. The reversible addition-break chain transfer polymerization (Raft) is used for active polymerization. A novel P4VP-b-PBz MA block copolymer was synthesized in ethanol solution. 鈫扺orm. 鈫扵he structure and size of aggregates can be effectively controlled by the change of P4VP in solvent-friendly segments. In addition, the process of structural transformation of P4VP-b-(PHPMA-co-PBz MA-triblock copolymers during self-assembly induced by polymerization was studied by random copolymerization.
【作者單位】： 華東理工大學(xué)材料科學(xué)與工程學(xué)院上海市先進(jìn)聚合物材料重點(diǎn)實(shí)驗(yàn)室;
【基金】：國(guó)家自然科學(xué)基金(Nos.51622301,51573046) 中央高�；究蒲袑ｍ�(xiàng)資金(Nos.B14018,WD1616010) 上海市曙光計(jì)劃(No.14SG29)資助項(xiàng)目~~
【分類號(hào)】：O631

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