西沙永興島大氣降水化學(xué)特征及來(lái)源分析
發(fā)布時(shí)間:2018-05-31 18:22
本文選題:南海 + 降水。 參考:《中國(guó)環(huán)境科學(xué)》2016年11期
【摘要】:于2013年對(duì)南海西沙永興島雨水進(jìn)行采集,分析了其主要陰陽(yáng)離子,利用PMF模型對(duì)不同離子組成的來(lái)源進(jìn)行解析并運(yùn)用Traj Stat軟件模擬后向氣團(tuán)軌跡污染物來(lái)源區(qū)域的分析.結(jié)果表明,永興島降水離子濃度順序?yàn)?Cl~-、SO_4~(2-)、NO_3~-和Na~+、Ca~(2+)、Mg~(2+)、NH_4~+、K~+.Na~+和Cl~-是降水中主要的陰陽(yáng)離子,表現(xiàn)出海洋性降水的特征.SO_4~(2-)、Mg~(2+)、K~+主要來(lái)源于海水,但SO_4~(2-)也受化石燃料燃燒等影響,而K~+可能受生物質(zhì)燃燒的影響.Ca~(2+)主要來(lái)源于土壤,少數(shù)來(lái)源于其他影響.NO_3~-主要來(lái)源于化石燃料燃燒釋放,而NH_4~+有多種來(lái)源,包括內(nèi)陸人為活動(dòng)的排放和海洋本身有機(jī)物降解過(guò)程釋放的影響.根據(jù)Redfield比,可以初步計(jì)算出降水中NO-3~-和NH_4~+對(duì)南海新生產(chǎn)力的貢獻(xiàn)約為4.8%~13.5%.后向氣團(tuán)軌跡表明,永興島降水的離子來(lái)源區(qū)域相對(duì)復(fù)雜,包括我國(guó)東北地區(qū)、南方區(qū)域,以及馬來(lái)西亞等國(guó)家、地區(qū)的影響,或者來(lái)源于南海局地的影響.
[Abstract]:In 2013, the rainwater of Yongxing Island, Xisha, Xisha, South China Sea was collected, and the main Yin and yang ions were analyzed. The sources of different ions were analyzed by PMF model and the source region of the air mass trajectory was simulated by Traj Stat software. The results showed that the order of precipitation ion concentration in Yongxing island was Cl~-, SO_4~ (2-), NO_3~- and Na~+, Ca~ (2+), Mg~ (2+), NH_4~+, K~+.Na~+ and Cl~- are the main Yin and yang ions in precipitation, showing the characteristics of marine precipitation,.SO_4~ (2-), Mg~ (2+), and K~+ mainly originate in the sea water, but they are also affected by the combustion of fossil fuels. It is mainly derived from the release of fossil fuel combustion, while NH_4~+ has a variety of sources, including the emission of inland human activities and the release of the degradation process of the marine organic matter. According to the Redfield ratio, the contribution of NO-3~- and NH_4~+ to the new productivity of the South China Sea in the precipitation can be estimated to be about 4.8%~13.5%. back air mass trajectory. The ion source regions of water are relatively complex, including the influence of the northeast region, the southern region, and the Malaysia and other countries, or the effects of the South China Sea.
【作者單位】: 東華理工大學(xué)核資源與環(huán)境教育部重點(diǎn)實(shí)驗(yàn)室大氣環(huán)境實(shí)驗(yàn)室;東華理工大學(xué)水資源與環(huán)境工程學(xué)院;中國(guó)科學(xué)院地球化學(xué)研究所環(huán)境地球化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室;中國(guó)環(huán)境科學(xué)研究院;中國(guó)科學(xué)院南海海洋研究所熱帶海洋環(huán)境國(guó)家重點(diǎn)實(shí)驗(yàn)室;
【基金】:國(guó)家自然科學(xué)基金資助項(xiàng)目(41663003,41203015,41425014) 東華理工大學(xué)?萍紕(chuàng)新團(tuán)隊(duì)科研啟動(dòng)基金項(xiàng)目(DHKT2015101);東華理工大學(xué)博士科研啟動(dòng)基金項(xiàng)目(DHBK2015327)
【分類(lèi)號(hào)】:X51;P426.612
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