本文選題：燒結(jié)除塵灰 + HCl-NaCl混合溶液　； 參考：《中南大學(xué)學(xué)報(bào)(自然科學(xué)版)》2016年10期

【摘要】：研究一種以鋼鐵冶金燒結(jié)機(jī)頭電除塵灰為原料,濕法浸取回收其中的氯化鉛并利用其制取一氧化鉛的工藝技術(shù)。采用HCl-NaCl混合溶液將燒結(jié)灰中的鉛以PbCl_4~(2-)形式絡(luò)合浸取回收。利用所回收的氯化鉛制備一氧化鉛。實(shí)驗(yàn)考察浸取工藝中多種因素對(duì)浸取效率的影響,研究浸取母液的循環(huán)使用效果和一氧化鉛制備過(guò)程的轉(zhuǎn)化條件。研究結(jié)果表明:在溫度為85~90℃,氯化鈉質(zhì)量濃度為250 g/L,工業(yè)鹽酸用量為25 m L/(100 g),富鉛燒結(jié)灰(尾泥)與HCl-NaCl混合溶液的固液比為1.0:3.0 g/m L,浸取時(shí)間為30 min的條件下,在浸取過(guò)程中鉛的浸取率在99.50%以上;冷析母液循環(huán)使用2次,鉛的總回收率達(dá)95.08%;碳酸鈉的加入量為其理論量的0.90~1.00倍,鉛的沉淀率為99.90%,轉(zhuǎn)化得到的沉淀在650℃煅燒5 h,得到的一氧化鉛產(chǎn)品純度為99.50%,達(dá)到HG/T 2325—2004標(biāo)準(zhǔn)中工業(yè)一級(jí)品的指標(biāo)要求。
[Abstract]:A wet leaching process for recovering lead chloride from iron and steel metallurgical sintering machine head as raw material and preparing lead oxide by wet leaching was studied. Lead in the sintered ash was extracted by HCl-NaCl mixed solution in the form of PbCl4 / 2). Lead oxide was prepared from recovered lead chloride. The influence of many factors on the extraction efficiency was investigated experimentally. The recycling effect of the mother liquor and the conversion conditions of the preparation of lead oxide were studied. The results show that at the temperature of 8590 鈩，

本文編號(hào)：1944093