本文選題：有機(jī)太陽能電池 + 光電特性��； 參考：《沈陽師范大學(xué)》2017年碩士論文

【摘要】：二十一世紀(jì)的今天,科技日新月異,技術(shù)迅猛發(fā)展。不可再生能源一方面嚴(yán)重污染環(huán)境,另一方面隨著人類的大量使用已經(jīng)日漸枯竭,必須發(fā)展一種高效綠色的清潔能源來應(yīng)對(duì)上述情況。近些年來,太陽能的光電技術(shù)成為了大部分科研工作者的工作重點(diǎn),這個(gè)范圍已經(jīng)成為最具發(fā)展前景、最有科研價(jià)值的方向。依據(jù)使用材質(zhì)的差異,我們可以將太陽能電池分成:硅太陽能電池、多元化合物薄膜太陽能電池、有機(jī)物太陽能電池和納米晶太陽能電池。與傳統(tǒng)的一些發(fā)電方法對(duì)比,太陽能電池具備大量?jī)?yōu)勢(shì):可再生,清潔易得無污染,安全無噪音,無燃料消耗,無地域限制,易于維護(hù),建設(shè)時(shí)間短,可大規(guī)模應(yīng)用。而有機(jī)太陽能電池?fù)碛斜阋�、質(zhì)量輕、體積小等優(yōu)點(diǎn),已成為光電科技領(lǐng)域關(guān)注的重中之重。本文主要研究的是應(yīng)用于薄膜太陽能電池上的硫代雙烯型金屬配合物近紅外染料。簡(jiǎn)要介紹了近紅外染料的分類、硫代雙烯型金屬配合物在國內(nèi)外的發(fā)展?fàn)顩r、合成方法和科研預(yù)期。以改善活性材料的穩(wěn)定性,改變活性材料的應(yīng)用時(shí)間為目的。同時(shí)為了提高有機(jī)太陽能電池的全光譜吸收,在研究和總結(jié)現(xiàn)存的有關(guān)文獻(xiàn)和專利的前提下,本文設(shè)計(jì)了一種含長(zhǎng)碳鏈的硫代雙烯鎳配合物作為電池的活性材料。由于碳鏈的延長(zhǎng),提高活性材料溶解性的同時(shí),也使得活性材料的最大吸收波長(zhǎng)隨溶劑極性增大而向長(zhǎng)波長(zhǎng)方向移動(dòng)。以萘酚為基礎(chǔ)原料,制備了一種烷氧基萘酚,然后與草酰氯進(jìn)行傅克反應(yīng),制備出烷氧基萘基乙二酮,最終合成了目標(biāo)化合物。本文制備并表征了兩種硫代雙烯型金屬配合物,它們的結(jié)構(gòu)是經(jīng)過紅外光譜、核磁共振氫譜以及核磁共振碳譜,而被徹底表征的;紫外光譜測(cè)試結(jié)果表明:兩種配合物在920nm左右都具有較強(qiáng)的紫外吸收;經(jīng)過熱重分析:兩種配合物對(duì)熱都具有較好的穩(wěn)定性。由此可以得出:在近紅外吸收方面這兩種硫代雙烯型金屬配合物都擁有極好的應(yīng)用價(jià)值。
[Abstract]:21 century today, science and technology with each passing day, rapid development of technology. On the one hand, non-renewable energy seriously pollutes the environment, on the other hand, with the extensive use of human beings, it is necessary to develop a kind of efficient and green clean energy to deal with the above situation. In recent years, photovoltaic technology of solar energy has become the focus of most scientific research workers, which has become the most promising and most valuable research direction. Solar cells can be divided into silicon solar cells, multicompound thin film solar cells, organic solar cells and nanocrystalline solar cells, depending on the material used. Compared with some traditional power generation methods, solar cells have a lot of advantages: renewable, clean and pollution-free, safe and noise free, no fuel consumption, no geographical restrictions, easy maintenance, short construction time, and can be applied on a large scale. Organic solar cells have the advantages of low cost, light weight and small size. In this paper, the near infrared dyes of thiobene-type metal complexes used in thin film solar cells are studied. The classification of near infrared dyes, the development of thiobenzene metal complexes at home and abroad, the synthetic methods and the prospect of scientific research are briefly introduced. In order to improve the stability of active materials and change the application time of active materials. At the same time, in order to improve the full spectral absorption of organic solar cells, on the premise of researching and summarizing the existing literatures and patents, a thiobenzene nickel complex containing long carbon chain was designed as the active material of the cell. Because of the prolongation of the carbon chain, the solubility of the active material is improved, and the maximum absorption wavelength of the active material shifts to the long wavelength with the increase of the solvent polarity. A alkoxy naphthol was prepared from naphthol and then reacted with oxaloyl chloride to prepare alkoxy naphthyl ethanedione. Finally, the target compound was synthesized. In this paper, two kinds of thiobenzene metal complexes were prepared and characterized. Their structures were characterized by IR, NMR and NMR carbon spectra. The UV spectra showed that the two complexes had strong UV absorption in 920nm and the thermogravimetric analysis showed that the two complexes had good thermal stability. It can be concluded that these two thiobenzene metal complexes have excellent application value in near infrared absorption.
【學(xué)位授予單位】：沈陽師范大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2017
【分類號(hào)】：O641.4

【參考文獻(xiàn)】

相關(guān)期刊論文 前10條

1 尚洋洋;陳永杰;張文秀;李郎楷;劉婷婷;;烷氧基苯基硫代雙烯合鎳的合成及光譜性能[J];沈陽化工大學(xué)學(xué)報(bào);2011年03期

2 高俊雄;苗青青;王澤清;高玉榮;馬廷麗;;硫代雙烯鎳近紅外染料的合成及性質(zhì)[J];精細(xì)化工;2011年09期

3 康麗;郭建博;李洪奎;楊景亮;廉靜;郭延凱;李海波;王瑜瑜;;氧化還原介體催化強(qiáng)化偶氮染料脫色研究進(jìn)展[J];河北工業(yè)科技;2010年06期

4 陳永杰;尚洋洋;張文秀;張靜;耿秀娟;谷亨達(dá);;四-(3,4-二甲氧基苯基)硫代雙烯合鎳的合成與光譜性能[J];精細(xì)化工;2010年11期

5 白青龍;張春花;夏道成;程傳輝;范昭奇;杜國同;;酞菁及類酞菁的結(jié)構(gòu)與紫外可見光譜研究[J];材料導(dǎo)報(bào);2010年07期

6 李路海;蔚慧;;金屬絡(luò)合染料電泳原理研究[J];信息記錄材料;2008年04期

7 鄭少琴;;有機(jī)顏料酞菁藍(lán)的合成及顏料化[J];染料與染色;2008年03期

8 王茜;鄭文偉;程海峰;門金鳳;楚增勇;;硫代雙烯型金屬配合物近紅外染料研究進(jìn)展[J];材料導(dǎo)報(bào);2007年01期

9 孫成才;霍冀川;雷永林;吳瑞榮;;近紅外吸收功能菁染料的研究進(jìn)展[J];材料導(dǎo)報(bào);2006年08期

10 高文濤,崔巖;三芳甲烷型隱色體氧化制備酸性染料的研究進(jìn)展[J];渤海大學(xué)學(xué)報(bào)(自然科學(xué)版);2005年02期

相關(guān)碩士學(xué)位論文 前4條

1 陳進(jìn)明;硫代雙烯型金屬配合物的合成及其光譜性質(zhì)的研究[D];長(zhǎng)春理工大學(xué);2009年

2 王茜;硫代雙烯型鎳配合物的合成及性能研究[D];國防科學(xué)技術(shù)大學(xué);2007年

3 丁慧敏;二硫代雙烯類金屬絡(luò)合物的合成及其性能研究[D];長(zhǎng)春理工大學(xué);2007年

4 洪愛真;胺基化殼聚糖微球吸附陰離子偶氮染料的研究[D];福建師范大學(xué);2003年

，

本文編號(hào)：1969461