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電滲析和反滲透耦合深度處理制革高鹽廢水的研究

發(fā)布時(shí)間:2018-12-21 08:46
【摘要】:針對(duì)制革行業(yè)"雙膜法"廢水回用工藝產(chǎn)生的高鹽廢水的特點(diǎn),通過(guò)電驅(qū)離子膜和反滲透膜的耦合,對(duì)制革高鹽廢水進(jìn)行了高效深度處理研究。結(jié)果表明,在電壓25 V、進(jìn)水體積流量30 L/h、脫鹽室循環(huán)體積流量500 L/h操作條件下,經(jīng)過(guò)電滲析分離,得到的濃縮鹽水TDS的質(zhì)量濃度在150 g/L以上,滿足皮革浸漬工序段用料要求;得到的脫鹽水TDS的質(zhì)量濃度8.2 g/L、COD為330 mg/L。脫鹽水在28℃、進(jìn)水體積流量900 L/h、回收率50%條件下,經(jīng)反滲透處理得到淡水TDS的質(zhì)量濃度72 mg/L、不含COD,水質(zhì)達(dá)到了GB/T 19923-2005的要求;產(chǎn)出濃水水質(zhì)與原水水質(zhì)相似,可返回電滲析工序。該工藝可有效提升系統(tǒng)的水回收利用率。
[Abstract]:According to the characteristics of high salt wastewater produced by "double membrane process" wastewater reuse in tannery industry, the high efficiency advanced treatment of high salt tannery wastewater was studied by coupling ion membrane with reverse osmosis membrane. The results show that under the conditions of voltage 25 V, influent volume flow 30 L / h, and desalination chamber circulation volume flow 500L / h, the concentration of TDS in concentrated brine is more than 150g / L after electrodialysis separation. Meet the requirements of leather impregnation process material; The mass concentration of desalted TDS is 8.2 g / L ~ (-1), which is 330 mg/L.. Under the conditions of desalination at 28 鈩,

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