機械合金化法制備AgCr觸頭材料及其性能研究
本文選題:電觸頭材料 + 機械合金化。 參考:《暨南大學(xué)》2010年碩士論文
【摘要】: 電觸頭主要負責(zé)接通、斷開電路及負載電流的任務(wù),由于它的特殊作用,電接觸材料的性能直接影響電子產(chǎn)品的可靠性、穩(wěn)定性、精度和使用壽命。在閉合和斷開的過程中觸頭受到電侵蝕是導(dǎo)致其不能正常工作的主要原因。因此開展抗電侵蝕性能強的電接觸材料的研究有重要的意義。 本文主要研究機械合金化法制備AgCr觸頭材料及其性能。首先,分析球磨轉(zhuǎn)速和球磨時間對球磨粉末物相、晶粒大小、微觀應(yīng)變和粉末形貌的影響,主要是用X射線衍射儀和掃描電子顯微鏡對粉末進行物相及形貌分析。其次,研究球磨轉(zhuǎn)速、球磨時間、球料比和燒結(jié)溫度等工藝參數(shù)對AgCr合金材料的密度、硬度、導(dǎo)電性、金相結(jié)構(gòu)的影響,總結(jié)出制備性能優(yōu)異的AgCr合金材料的工藝。最后,通過對電路電流及通斷比的變化、觸頭接觸電阻的變化和接觸表面形貌及成分的分析研究,可綜合分析觸頭材料的電接觸性能。通過比較AgCr觸頭、銅基覆銀觸頭、AgSnO2觸頭在電流作用下的接觸性能,檢驗AgCr觸頭是否具有較強的抗電侵蝕能力。 研究結(jié)果表明:當(dāng)球磨轉(zhuǎn)速達到一定值,球磨到一定時間,Cr相能部分固溶到Ag相中。適當(dāng)?shù)那蚰スに噮?shù)和燒結(jié)溫度可以制備出性能相對優(yōu)異的AgCr合金,其制備的AgCr(Cr含量12 wt%),密度為9.62 g/cm3,硬度為122.3 HV,導(dǎo)電率4.03μΩ·cm,同時燒結(jié)體金相結(jié)構(gòu)表明該工藝參數(shù)下制備的觸頭材料組織分散較均勻,無明顯團聚現(xiàn)象,具有很好的開發(fā)和應(yīng)用前景。 AgCr觸頭電接觸性能分析表明:分別在相同測試條件下,發(fā)現(xiàn)AgCr觸頭電性能要優(yōu)于銅基覆銀觸頭;而與AgSnO2觸頭相比,AgCr對稱觸頭材料轉(zhuǎn)移量更大,但是AgSnO2觸頭接觸表面有裂紋生成,并且閉合分斷電流達10萬次后,AgCr對稱觸頭保持接觸電阻低而穩(wěn)定,同時電路通斷比沒變化。總體評價:AgCr觸頭具有較好的電接觸性能。
[Abstract]:The electrical contact is mainly responsible for the task of turning on, disconnecting circuit and load current. Because of its special function, the performance of electrical contact material directly affects the reliability, stability, precision and service life of electronic products. Electrical erosion of the contact during closure and disconnection is the main cause of its failure to work properly. Therefore, it is of great significance to study the electrical contact materials with strong resistance to electrical erosion. In this paper, the preparation and properties of AgCr contact materials by mechanical alloying are studied. Firstly, the effects of ball milling speed and milling time on the phase, grain size, micro strain and powder morphology of ball milling powder were analyzed. The phase and morphology of the powder were analyzed by X-ray diffractometer and scanning electron microscope. Secondly, the effects of milling speed, milling time, ratio of ball to material and sintering temperature on the density, hardness, electrical conductivity and metallographic structure of AgCr alloy were studied, and the process of preparing AgCr alloy with excellent properties was summarized. Finally, the electrical contact properties of the contact materials can be comprehensively analyzed by analyzing the changes of the circuit current, the on-off ratio, the contact resistance, the morphology and the composition of the contact surface. By comparing the contact properties of AgCr contacts and copper based silver coated contacts with AgSnO2 contacts under the action of electric current, the results show that the AgCr contacts have strong resistance to electric erosion. The results show that when the ball milling speed reaches a certain value, The Cr phase energy is partially dissolved into Ag phase by ball milling to a certain time. AgCr alloys with relatively excellent properties can be prepared by proper ball milling process parameters and sintering temperature. The AgCr-Cr content is 12 wtlong, the density is 9.62 g / cm ~ 3, the hardness is 122.3 HVand the conductivity is 4.03 渭 惟 路cm. At the same time, the microstructure of the sintered contact material is uniform and there is no obvious agglomeration. The analysis of the electrical contact properties of AgCr contacts shows that the electrical properties of AgCr contacts are superior to those of copper based silver contacts under the same test conditions, and the amount of material transfer of AgCr symmetrical contacts is larger than that of AgSnO2 contacts. However, there are cracks on the contact surface of AgSnO2 contacts, and the AgCr symmetrical contacts keep the contact resistance low and stable after the closing breaking current reaches 100000 times, while the on-to-break ratio of the circuit does not change. The general evaluation shows that: AgCr contacts have better electrical contact performance.
【學(xué)位授予單位】:暨南大學(xué)
【學(xué)位級別】:碩士
【學(xué)位授予年份】:2010
【分類號】:TM24
【參考文獻】
相關(guān)期刊論文 前10條
1 徐炯,朱麗慧,余海峰;銀基觸頭材料電弧作用下的失效及其機理[J];材料科學(xué)與工程學(xué)報;2003年04期
2 張昆華,管偉明,孫加林,盧峰,陳敬超,周曉龍,杜焰;AgSnO_2電接觸材料的制備和直流電弧侵蝕形貌特征[J];稀有金屬材料與工程;2005年06期
3 郭迎春;耿永紅;陳松;張昆華;管偉明;;電觸點直流電侵蝕研究[J];稀有金屬材料與工程;2007年S3期
4 榮命哲,馮建興,楊武;低壓電器電觸頭材料的電弧侵蝕[J];低壓電器;1998年01期
5 劉向軍;;開關(guān)電器觸頭熔焊機理分析[J];低壓電器;2006年09期
6 李震彪;吳細秀;魏梅芳;;短弧對汽車繼電器觸頭動熔焊的影響[J];低壓電器;2007年01期
7 李震彪;徐金玲;黃良;徐堅;;電磁繼電器觸點動熔焊機理分析[J];低壓電器;2007年05期
8 李海軍,孫秀霞;繼電器觸頭的電蝕機理研究[J];電子產(chǎn)品可靠性與環(huán)境試驗;2005年03期
9 徐安蓮,劉守平,周上祺,陳玉安;機械合金化的研究進展[J];重慶大學(xué)學(xué)報(自然科學(xué)版);2005年11期
10 朱心昆,林秋實,陳鐵力,程抱昌,曹建春;機械合金化的研究及進展[J];粉末冶金技術(shù);1999年04期
相關(guān)碩士學(xué)位論文 前4條
1 邱小勇;銀氧化錫復(fù)合材料的制備[D];中南大學(xué);2005年
2 簡德湘;高能球磨法制備AgSnO_2電接觸材料的研究[D];天津大學(xué);2004年
3 郭自鵬;Ag基梯度材料的制備及物理性質(zhì)[D];西南交通大學(xué);2007年
4 葉家健;AgMeO觸頭材料制備及抗電弧侵蝕性能的研究[D];華中科技大學(xué);2007年
,本文編號:1987453
本文鏈接:http://sikaile.net/shekelunwen/minzhuminquanlunwen/1987453.html