In our work we will interest in the study of self-accelerating decompositiontemperature TSADTof pyrotechnic compounds such as black powder （75%KNO310%C and15%S）, and another mixture which contains （75%KClO415%CrCl3and10%S）. We willdiscuss the application of the DSC traces after advanced kinetic analysis for thedetermination of the Time to Maximum Rate under adiabatic conditions （TMRad）. In thiswork, attention will be focused on the applicability of AKTS-thermo kinetics software onthe determinati... 

【文章來源】：北京理工大學(xué)北京市 211工程院校 985工程院校

【文章頁數(shù)】：63 頁

【學(xué)位級別】：碩士

【文章目錄】：
Abstract
Figures
Tables
Chapter 1 Introduction
Chapter 2 Theoritical Part
    2.1 Theoretical models
        2.1.1 Model of Semenov
        2.1.2 Model of Franck-Kamenetskii
        2.1.3 Model of Thomas
        2.1.4 Summing up
    2.2 Thermal techniques used in hazard evaluation of pyrotechnics
        2.2.1 Shelf life
        2.2.2 Explosion delay
        2.2.3 Thermo stability threshold
        2.2.4 500 day’s cook-off temperature
        2.2.5 Approximate time to explosion
        2.2.6 Self Accelerating Decomposition Temperature (SADT)
    2.3 Evaluation of the decomposition kinetics
        2.3.1 Differential isoconversional concept (basics)
        2.3.2 Ozawa-Flynn-Wall Analysis
        2.3.3 ASTM E698
Chapter 3 Experimental Part
    3.1 Introduction
    3.2 Experiments
        3.2.1 Samples
        3.2.2 Differential scanning calorimetry (DSC)
        3.2.3 Thermal decomposition kinetics
        3.2.4 Thermal Decomposition of Energetic Materials by DSC
        3.2.5 Determination of the kinetic characteristics
        3.2.6 Adiabatic Conditions: Calculation of TMRad from DSC Experiments
        3.2.7 Calculation of SADT
Chapter 4 Conclusion
References
Appendix 1: Heat flow of black powder (KNO375%, C 10%, S 15%)
Appendix 2: Heat flow of pyrotechnic compound (KClO475% CrCl315% S 10%)
Appendix 3: The calculation of heat specific (Cp) of the systems (Samples)
Acknowledgements
About the Author


【參考文獻(xiàn)】：
期刊論文
[1]加速量熱儀在物質(zhì)熱穩(wěn)定性研究中的應(yīng)用[J]. 傅智敏,黃金印,錢新明,馮長根.  火災(zāi)科學(xué). 2001(03)
[2]用加速量熱儀研究KClO3/CuO/S/Mg-Al/C6Cl6的熱分解[J]. 錢新明,王耘,馮長根,鄭嬈.  物理化學(xué)學(xué)報(bào). 2001(01)



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