金屬有機(jī)化學(xué)溶液法REBa 2 Cu 3 O 7-x 超導(dǎo)涂層導(dǎo)體的厚度效應(yīng)和人工釘扎性能
發(fā)布時(shí)間:2021-11-22 18:25
自高溫超導(dǎo)材料被發(fā)現(xiàn)以來,其高載流能力在電力系統(tǒng)中的應(yīng)用前景吸引了人們廣泛關(guān)注。超導(dǎo)在電力方面應(yīng)用的關(guān)鍵問題是獲得低成本、高臨界電流的線帶材。近年來基于薄膜外延技術(shù)發(fā)展起來的REBa2CuO7-x(REBCO)涂層導(dǎo)體(即第二代高溫超導(dǎo)帶材)已經(jīng)在全球范圍內(nèi)正在以不同技術(shù)路線逐步實(shí)現(xiàn)產(chǎn)業(yè)化批量化制備。高品質(zhì)REBa2Cu3O7-x超導(dǎo)膜的制造工藝,如脈沖激光沉積(PLD),共蒸發(fā)(CE),化學(xué)氣相沉積(CVD)液相外延(LPE)和金屬有機(jī)沉積(MOD)等的研究已經(jīng)取得了重大進(jìn)展。這些制備方法可以產(chǎn)生高取向度的超導(dǎo)薄膜,并獲得了高性能涂層導(dǎo)體。在不同沉積工藝中,不降低臨界電流密度的情況下實(shí)現(xiàn)膜厚度的有效增加,均是一個(gè)重要的研究問題。MOD是實(shí)現(xiàn)涂層導(dǎo)體低成本、批量化制備非常有優(yōu)勢(shì)的途徑之一。目前,國內(nèi)外研究團(tuán)隊(duì)在這方面已經(jīng)做了很多工作,采用該方法獲得的超導(dǎo)臨界電流已經(jīng)達(dá)到了300-500 A/cm(77K,自場(chǎng))。在MRI、能量存儲(chǔ)系統(tǒng)、發(fā)電機(jī)、發(fā)動(dòng)機(jī)、電纜、超導(dǎo)線材和帶材、加速...
【文章來源】:上海大學(xué)上海市 211工程院校
【文章頁數(shù)】:126 頁
【學(xué)位級(jí)別】:博士
【文章目錄】:
摘要
ABSTRACT
Chapter 1. Introduction and Literature Review
1.1 Brief History of Superconductivity
1.1.1 Introduction to superconductor
1.1.2 Type of superconductors
1.1.3 Pinning mechanism in type Ⅱ superconductors
1.2 Key Issues for Improving Properties of YBa_2Cu_3O_(7-x)
1.2.1 Dependence of critical current density on film thickness
1.2.2 Vortex pinning in YBa_2Cu_3O_(7-x) films
1.2.3 Weak superconducting coupling across grain boundaries
1.3 REBa_2Cu_3O_(7-x) superconductor coated conductors
1.4 REBa_2Cu_3O_(7-x) Thin Film Growth Technology
1.4.1 Physical methods
1.4.2 Chemical methods
Chapter 2.Experimental Method and Characterization Techniques
2.1 Motivation
2.2 Preparation of REBa_2Cu_3O_(7-x) Coated Conductors
2.3 Techniques of Characterization and Measurements
2.3.1 Microstructure characterization
2.3.2 Superconducting properties
Chapter 3. Thick REBa_2Cu_3O_(7-x) Superconducting Films by Single Coating of Low-Fluorine MOD
3.1 Introduction
3.2 Experimental Details
3.3 Structural Analysis
3.4 The Superconducting Properties
3.5 Summary
Chapter 4. Enhanced Flux Pinning in YBaCuO_(7-x) Films with Co-Doping SrZrO_3 and Dy_2O_3 Nanoparticles
4.1 Introduction
4.2 Experimental Details
4.3 Structural Analysis
4.4 Superconducting Properties
4.4.1 Self-field performance
4.4.2 In-field performance
4.5 Summary
Chapter 5. Artificial Bilayers of YDy_(0.5)Ba_2Cu_3O_(7-δ) with SrZrO_3 and BaZrO_3 Interlayers
5.1 Introduction
5.2 Experimental Details
5.3 Structural Analysis
5.4 The Superconducting Properties
5.4.1 Self-filed performance
5.4.2 In-field properties
5.5 Summary
Chapter 6. Artificial Bilayers of YDyBCO+Dy211/ YDyBCO
6.1 Introduction
6.2 Experiment Details
6.3 Structural Analysis
6.4 Superconducting Properties
6.4.1 Self-field performance
6.4.2 In-field properties
6.5 Summary
Chapter 7. Conclusions and Further Work Proposed
7.1 Conclusions
7.2 Further Work Proposed
REFERENCES
AUTHOR PUBLICATIONS
ACKNOWLEDGEMENTS
【參考文獻(xiàn)】:
期刊論文
[1]SUPERCONDUCTIVITY ABOVE LIQUID NITROGEN TEMPERATURE IN Ba-Y-Cu OXIDES[J]. 趙忠賢,陳立泉,楊乾聲,黃玉珍,陳賡華,唐汝明,劉貴榮,崔長(zhǎng)庚,陳烈,王連忠,郭樹權(quán),李山林,畢建清. Science Bulletin. 1987(10)
本文編號(hào):3512224
【文章來源】:上海大學(xué)上海市 211工程院校
【文章頁數(shù)】:126 頁
【學(xué)位級(jí)別】:博士
【文章目錄】:
摘要
ABSTRACT
Chapter 1. Introduction and Literature Review
1.1 Brief History of Superconductivity
1.1.1 Introduction to superconductor
1.1.2 Type of superconductors
1.1.3 Pinning mechanism in type Ⅱ superconductors
1.2 Key Issues for Improving Properties of YBa_2Cu_3O_(7-x)
1.2.1 Dependence of critical current density on film thickness
1.2.2 Vortex pinning in YBa_2Cu_3O_(7-x) films
1.2.3 Weak superconducting coupling across grain boundaries
1.3 REBa_2Cu_3O_(7-x) superconductor coated conductors
1.4 REBa_2Cu_3O_(7-x) Thin Film Growth Technology
1.4.1 Physical methods
1.4.2 Chemical methods
Chapter 2.Experimental Method and Characterization Techniques
2.1 Motivation
2.2 Preparation of REBa_2Cu_3O_(7-x) Coated Conductors
2.3 Techniques of Characterization and Measurements
2.3.1 Microstructure characterization
2.3.2 Superconducting properties
Chapter 3. Thick REBa_2Cu_3O_(7-x) Superconducting Films by Single Coating of Low-Fluorine MOD
3.1 Introduction
3.2 Experimental Details
3.3 Structural Analysis
3.4 The Superconducting Properties
3.5 Summary
Chapter 4. Enhanced Flux Pinning in YBaCuO_(7-x) Films with Co-Doping SrZrO_3 and Dy_2O_3 Nanoparticles
4.1 Introduction
4.2 Experimental Details
4.3 Structural Analysis
4.4 Superconducting Properties
4.4.1 Self-field performance
4.4.2 In-field performance
4.5 Summary
Chapter 5. Artificial Bilayers of YDy_(0.5)Ba_2Cu_3O_(7-δ) with SrZrO_3 and BaZrO_3 Interlayers
5.1 Introduction
5.2 Experimental Details
5.3 Structural Analysis
5.4 The Superconducting Properties
5.4.1 Self-filed performance
5.4.2 In-field properties
5.5 Summary
Chapter 6. Artificial Bilayers of YDyBCO+Dy211/ YDyBCO
6.1 Introduction
6.2 Experiment Details
6.3 Structural Analysis
6.4 Superconducting Properties
6.4.1 Self-field performance
6.4.2 In-field properties
6.5 Summary
Chapter 7. Conclusions and Further Work Proposed
7.1 Conclusions
7.2 Further Work Proposed
REFERENCES
AUTHOR PUBLICATIONS
ACKNOWLEDGEMENTS
【參考文獻(xiàn)】:
期刊論文
[1]SUPERCONDUCTIVITY ABOVE LIQUID NITROGEN TEMPERATURE IN Ba-Y-Cu OXIDES[J]. 趙忠賢,陳立泉,楊乾聲,黃玉珍,陳賡華,唐汝明,劉貴榮,崔長(zhǎng)庚,陳烈,王連忠,郭樹權(quán),李山林,畢建清. Science Bulletin. 1987(10)
本文編號(hào):3512224
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