藏北羌塘上侏羅統(tǒng)—下白堊統(tǒng)勝利河油頁(yè)巖單體烴碳同位素研究
發(fā)布時(shí)間:2018-10-05 06:51
【摘要】:上侏羅統(tǒng)—下白堊統(tǒng)勝利河油頁(yè)巖位于北羌塘盆地與中央隆起之間的過(guò)渡帶上,呈北西西—南東東向展布,長(zhǎng)約30km。油頁(yè)巖含有豐富的正烷烴、類異戊二烯烴、萜類化合物、甾類化合物和芳香烴化合物。正構(gòu)烷烴呈前高后低的單峰型分布,nC17、nC_(19)為主峰碳,∑C21-/∑C22+比值范圍為0.78~3.43,均值為1.57,輕烴組分占有絕對(duì)優(yōu)勢(shì),OEP值介于0.77~1.12之間,平均值0.95,接近平衡值1.00;Pr/Ph值介于0.33~1.28之間,平均值0.71,絕大多數(shù)樣品Pr/Ph值小于1.0,顯示弱的植烷優(yōu)勢(shì);萜烷豐度順序?yàn)槲瀛h(huán)三萜烷三環(huán)萜烷;規(guī)則甾烷呈不對(duì)稱的"V"字形分布,表現(xiàn)為C27C29C28的分布特征。油頁(yè)巖正構(gòu)烷烴碳同位素δ13 C值介于-29.89‰~-23.73‰之間(平均-26.99‰),為略為傾斜的平直型分布,其不同碳數(shù)單體烴同位素及生物標(biāo)志物特征均顯示有機(jī)質(zhì)主要來(lái)自低等生物菌藻類。類異茂二烯烷烴姥鮫烷和植烷碳同位素δ13 C值分別介于-30.72‰~-24.57‰(平均-28.39‰)和-29.87‰~-27.24‰(平均-28.52‰)之間,兩者δ13 C值非常相似。與通常情況不同的是,姥鮫烷和植烷碳同位素明顯比正構(gòu)烷烴輕,姥鮫烷平均輕1.59‰(范圍0.02‰~3.66‰),植烷平均輕1.84‰(范圍0.37‰~3.69‰);分析認(rèn)為水體中溝鞭藻或群體綠藻—叢綠藻Botryococus的繁盛可能是導(dǎo)致此碳同位素異常的原因。鏡檢顯示有機(jī)質(zhì)類型為腐殖腐泥型(Ⅱ1)和腐泥腐殖型(Ⅱ2),鏡質(zhì)體反射率(Ro)值介于0.37~0.9%之間,均值為0.55%,有機(jī)質(zhì)處于未成熟—低成熟階段。熱解峰溫Tmax值、孢粉顏色、飽和烴生物標(biāo)志化合物成熟度參數(shù)和芳香烴甲基菲成熟度指數(shù)也證實(shí)有機(jī)質(zhì)處于未成熟—低成熟階段。
[Abstract]:The Shengghe oil shale of Upper Jurassic-Lower Cretaceous is located in the transitional zone between the northern Qiangtang basin and the central uplift. Oil shale is rich in n-alkanes, isoprene hydrocarbons, terpenoids, steroids and aromatic compounds. The distribution of n-alkanes is a single peak of the former high and the lower. The 鈭,
本文編號(hào):2252427
[Abstract]:The Shengghe oil shale of Upper Jurassic-Lower Cretaceous is located in the transitional zone between the northern Qiangtang basin and the central uplift. Oil shale is rich in n-alkanes, isoprene hydrocarbons, terpenoids, steroids and aromatic compounds. The distribution of n-alkanes is a single peak of the former high and the lower. The 鈭,
本文編號(hào):2252427
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