本文選題：油頁巖　切入點：催化劑　出處：《吉林大學》2017年碩士論文　論文類型：學位論文

【摘要】：石油資源的逐漸枯竭、低油價和巨大的儲存量,甚至是全球能源的預期增長,在近幾年,引起了全球范圍內(nèi)越來越多對油頁巖的利用的關(guān)注,油頁巖被看作是緩解石油供應壓力的主要的可選擇來源。在這項研究中,評估了樺甸(HD)油頁巖與不同催化劑(即氫氧化鈉和硝酸鈉),金屬氯化物(即亞錫、鉬和鋅的氯化物)以及(硝酸鉀)相互作用的的動力學參數(shù)。通過傅立葉變換紅外光譜(FTIR)、X-射線衍射(XRD)、熱重量(TGA)分析、氣相色譜質(zhì)譜(GC-MS)、元素分析和掃描電子顯微鏡進行了表征油頁巖和固體殘留物。另外,通過Coats-Redfern方法對動力學參數(shù)(活化能E和頻率因子A)進行計算。結(jié)果顯示,對油頁巖的熱解高溫分解來說,添加金屬氯化物的影響大于其他催化劑的作用。用催化劑處理的樣品的活化能表現(xiàn)出最高的下降。與未經(jīng)催化劑處理的樣品相比,特別是樣品相比,金屬氯化物催化劑的存在(SnCl2、MoCl5和ZnCl2),分別下降15.1 kJ mol-1,10.66 kJ mol-1,20.58 kJ mol-1。此外,硝酸鈉和硝酸鉀降低約7.26 kJ mol-1和4.98 kJ mol-1。這項研究打開了一個嶄新且可利用的方法,使得油頁巖可以在低溫下被處理,以及提高樺甸油頁巖的利用率來生產(chǎn)在催化狀態(tài)下的液態(tài)和氣態(tài)的油頁巖。
[Abstract]:The gradual depletion of oil resources, low oil prices and huge reserves, and even the expected growth of global energy resources, have attracted more and more attention to the utilization of oil shale worldwide in recent years. Oil shale is seen as a major alternative source of oil supply pressure. In this study, the Huadian HD oil shale was evaluated with different catalysts (sodium hydroxide and sodium nitrate), metal chlorides (stannous oxide), Kinetic parameters for the interaction between molybdenum and zinc (chloride) and (potassium nitrate). Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRDX), thermogravimetric (TGA) analysis, Gas chromatography-mass spectrometry (GC-MS), elemental analysis and scanning electron microscopy (SEM) were used to characterize oil shale and solid residues. In addition, kinetic parameters (activation energy E and frequency factor A) were calculated by Coats-Redfern method. For the pyrolysis and high temperature decomposition of oil shale, the effect of adding metal chloride is greater than that of other catalysts. The activation energy of the samples treated with catalyst shows the highest decrease. In particular, compared with the sample, the presence of metal chloride catalyst SnCl2MoCl5 and ZnCl2 + decreased by 15.1 kJ / mol -1 (10.66 kJ / mol -1) and 20.58 kJ / mol ~ (-1), respectively. In addition, sodium nitrate and potassium nitrate decreased by about 7.26 kJ / mol-1 and 4.98 kJ / mol ~ (-1) respectively. This study opens up a new and available method, So that oil shale can be treated at low temperature, and the utilization rate of Huadian oil shale can be improved to produce liquid and gaseous oil shale in catalytic state.
【學位授予單位】：吉林大學
【學位級別】：碩士
【學位授予年份】：2017
【分類號】：TE662

【相似文獻】

相關(guān)期刊論文 前10條

1 ;Design of database management system of oil shale resource evaluation based on GIS[J];Global Geology;2012年02期

2 楊蘭和;Semi-Industrial Test of Underground Coal Gasification In Well No.2 in Xinhe, Xuzhou[J];Journal of China University of Mining & Technology;1999年02期

3 ;Determination of disperse elements in black shale by inductively coupled plasma mass spectrometry[J];Chinese Science Bulletin;1999年S2期

4 ;The Xiamaling oil shale generated through Rhodophyta over 800 Ma ago[J];Science in China(Series D:Earth Sciences);2007年04期

5 ;Oil Shale Resources and Its Distribution in China[J];China Oil & Gas;2007年03期

6 ;Present Development Status of Oil Shale[J];China Chemical Reporter;2008年33期

7 ;Combustion characteristics of Daqing oil shale and oil shale semi-cokes[J];Mining Science and Technology;2009年03期

8 ;Test method and experimental research on resistance of oil shale under high temperature[J];Global Geology;2012年03期

9 LI YanJun;LIU Huan;ZHANG LieHui;LU ZongGang;LI QiRong;HUANG YongBin;;Lower limits of evaluation parameters for the lower Paleozoic Longmaxi shale gas in southern Sichuan Province[J];Science China(Earth Sciences);2013年05期

10 Abd El-Rahiem F.H.;Hassan M.S.;Selim K.A.;Abdel-Khalek N.A.;;Characterization and beneficiation of the Egyptian black shale for possible extraction of organic matter[J];International Journal of Mining Science and Technology;2014年02期

相關(guān)會議論文 前5條

1 ;Preliminary Study on PAHs Distribution in High-grade Oil Shale and Its Spontaneous Combustion Product in Fushun,Liaoning Province[A];中國科學院地質(zhì)與地球物理研究所2007學術(shù)論文匯編(第四卷)[C];2008年

2 J.Pasava;B.Kribek;P.Dobes;I.Varrin;K.Zak;;Geochemistry and origin of tin-polymetallic sulfide deposits hosted by the Devonian black shale series near Dachang,Guangxi,China[A];中國科學院地質(zhì)與地球物理研究所二○○四學術(shù)論文匯編·第三卷(油氣·礦產(chǎn)·水資源)[C];2004年

3 Chen Qiao;Liu Hong;Wang Li-sha;Fan Xiao-wen;Wang Qi-jun;;The Research on Brittleness of Shale in Longmaxi Formation,the Southeastern Chongqing Area[A];第二屆全國特殊氣藏開發(fā)技術(shù)研討會優(yōu)秀論文集[C];2013年

4 ;The Xikuangshan Sb deposit hosted by the Upper Devonian black shale series,Hunan,China[A];中國科學院地質(zhì)與地球物理研究所二○○四學術(shù)論文匯編·第三卷(油氣·礦產(chǎn)·水資源)[C];2004年

5 ;NANJING INSTITUTE OF GEOLOGY AND MINERAL RESOURCES——THE SUMMARY OF SCIENTIFIC RESEARCH WORK[A];中國地質(zhì)科學院文集（1983中英文合訂本）[C];1983年

相關(guān)碩士學位論文 前3條

1 Marina Benino;[D];山東大學;2017年

2 RABIEA ABAKAR YAHYA ABAKAR;油頁巖在不同催化劑預熱處理條件下熱解研究[D];吉林大學;2017年

3 羅蘭德（NGUIMBI Guy Roland）;電加熱高溫分解樺甸油頁巖的實驗及仿真[D];吉林大學;2012年

，

本文編號：1632786