安徽宣城茶亭銅金礦床賦礦石英閃長玢巖鋯石U-Pb年齡及巖石成因
本文選題:巖石成因 + U-Pb年齡 ; 參考:《高校地質(zhì)學(xué)報(bào)》2017年04期
【摘要】:安徽宣城茶亭Cu-Au礦床是長江中下游成礦帶內(nèi)新發(fā)現(xiàn)的一個(gè)斑巖型礦床。文章對該礦床賦礦石英閃長玢巖進(jìn)行了鋯石LA-ICP-MS U-Pb同位素年齡及巖石主量與微量元素、Sr-Nd同位素和鋯石Lu-Hf同位素分析,旨在探討其巖漿起源和巖石成因。鋯石U-Pb同位素年齡測定結(jié)果顯示,賦礦石英閃長玢巖形成年齡為137.8±1.3 Ma(MSWD=0.72),為早白堊世巖漿活動(dòng)的產(chǎn)物。巖石主量元素顯示其具富堿富鈉特征,為亞堿性準(zhǔn)鋁質(zhì)高鉀鈣堿性系列巖石。巖石微量元素顯示其富集大離子親石元素K、Rb、Sr、Ba和輕稀土元素,弱富集Zr和Hf,虧損高場強(qiáng)元素Nb、Ta、Ti等,稀土元素配分型式表現(xiàn)為無明顯Eu異常。巖石(~(87)Sr/~(86)Sr)_i值介于0.706403~0.707903之間,ε_(Nd)(t)值介于-7.4~-13.3之間(t=137.8 Ma)。鋯石ε_(Hf)(t)值為-4.25~-11.75(t=137.8 Ma)。主量元素、微量元素、Sr-Nd同位素和鋯石Hf同位素地球化學(xué)特征均指示,賦礦石英閃長玢巖可能是富集巖石圈地幔與揚(yáng)子下地殼物質(zhì)部分熔融形成的巖漿混合后侵位的產(chǎn)物。對比長江中下游成礦帶斷隆區(qū)和斷凹區(qū)侵入巖發(fā)現(xiàn),宣城茶亭礦床賦礦石英閃長玢巖與長江中下游成礦帶斷凹區(qū)(寧蕪、廬樅礦集區(qū)等)侵入巖,無論是巖石主量與微量元素地球化學(xué)特征還是同位素地球化學(xué)特征都存在一定差異,而與斷隆區(qū)(銅陵礦集區(qū))賦礦巖漿巖表現(xiàn)出一致性,暗示宣城茶亭礦床賦礦石英閃長玢巖與長江中下游成礦帶斷隆區(qū)巖漿巖有著基本一致的成巖物質(zhì)來源和巖石成因機(jī)制,是富集巖石圈地幔熔融巖漿及其引起的下地殼物質(zhì)部分熔融巖漿發(fā)生巖漿混合作用并伴隨著一定程度的分離結(jié)晶作用進(jìn)而淺成侵位形成。
[Abstract]:The Cu-Au deposit in Xuancheng, Anhui Province is a porphyry deposit found in the middle and lower reaches of the Yangtze River.In this paper, zircon LA-ICP-MS U-Pb isotopic age, major rock mass and trace element Sr ND isotopes and zircon Lu-Hf isotopes are analyzed for the diorite porphyrite bearing ore in the deposit. The purpose of this paper is to discuss the magmatic origin and petrogenesis of the porphyrite.The U-Pb isotopic dating of zircon shows that the age of formation of diorite porphyrite is 137.8 鹵1.3MaMS-WDX 0.72, which is the product of early Cretaceous magmatism.The main elements of the rocks show that they are rich in alkali and sodium, and belong to the subalkaline pseudo-aluminous high potassium calc-alkaline series rocks.The trace elements in the rocks show that they are rich in the large ion lithophile element K ~ (2 +) Rb ~ (2 +) Sr ~ (2 +) Ba and light rare earth elements, and are weakly enriched in Zr and HF, and depleted in the high field strength element Nb ~ (10) Ta-Ti, etc. The REE partitioning patterns show no obvious EU anomalies.The value of S / R / 86 / S / S / S / I is between 0.706403 and 0.707903, and the value of 蔚 _ S / N _ (D) is between -7.4 ~ 13.3 ~ 137.8 Ma ~ (-1).The value of zircon 蔚 -Hfnn is -4.25 ~ 11.75 ~ 137.8 Ma ~ (-1) ~ (-1) ~ (-1) ~ (-1) ~ (-1) ~ (-1) ~ (-1).The geochemical characteristics of major elements, trace element Sr ND isotopes and zircon HF isotopes indicate that the ore-bearing diorite porphyrite may be the product of magmatic emplacement resulting from the partial melting of the enriched lithospheric mantle and the lower Yangtze crust material.In contrast to the intrusive rocks in the middle and lower reaches of the Yangtze River in the fault-uplift and fault-sag areas, it is found that the Xuancheng Tea Ting deposit is filled with diorite porphyrite and the fault-sag areas of the middle and lower reaches of the Yangtze River (Ningwu, Luzong ore concentration, etc.) intrusive rocks.There are some differences in the geochemical characteristics of major and trace elements or isotopic geochemistry of rocks, but are consistent with the ore-bearing magmatic rocks in the faulted uplift area (Tongling ore concentration area).It is suggested that the ore-bearing diorite porphyrite is basically consistent with the magmatic rocks in the fault-uplift area of the middle and lower reaches of the Yangtze River.It is the magmatic mixing of enriched lithospheric mantle molten magma and the partial melting magma of the lower crust, which is accompanied by a certain degree of separation and crystallization and then the formation of superficial emplacement.
【作者單位】: 合肥工業(yè)大學(xué)資源與環(huán)境工程學(xué)院;安徽省地質(zhì)礦產(chǎn)勘查局322地質(zhì)隊(duì);
【基金】:國家自然科學(xué)基金(41472066) 安徽省國土資源科技項(xiàng)目(2014K3)資助
【分類號】:P588.1;P618.2
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