TiAlSiN納米復合涂層的改性研究現(xiàn)狀及發(fā)展
發(fā)布時間:2018-05-22 16:09
本文選題:TiAlSiN涂層 + 改性。 參考:《表面技術》2017年08期
【摘要】:隨著切削技術向高速、高效、高精、綠色、智能方向發(fā)展,切削加工對刀具及涂層性能提出了更高的要求,以TiAlSiN涂層為代表的四元硬質(zhì)涂層發(fā)展迅速。綜述了單層TiAlSiN納米復合涂層的制備工藝、結(jié)構(gòu)與性能特點,根據(jù)TiAlSiN單層涂層存在低韌性和低結(jié)合強度的問題,提出了對TiAlSiN涂層改性研究的必要性。綜述了結(jié)構(gòu)改性、成分改性以及二者相結(jié)合改性TiAlSiN涂層的制備工藝、結(jié)構(gòu)與性能特點,指出了納米多層結(jié)構(gòu)的TiAlSiN涂層中存在的橫向?qū)娱g界面對原子的擴散具有良好的阻礙作用,涂層的抗氧化性由此被提高,涂層硬度等力學性能受多層結(jié)構(gòu)的調(diào)制層成分、調(diào)制周期等因素影響而被提高或降低。介紹了C、Cu、Cr、V等合金化元素在TiAlSiN涂層中的作用效果,C元素在涂層中具有減摩作用,Cu元素的主要作用是增強涂層與基體的結(jié)合,Cu、Cr、V元素在涂層中均使涂層硬度不同程度降低,提出了最大限度發(fā)揮添加元素與層間界面結(jié)構(gòu)的協(xié)同作用來獲取最佳性能的納米多層結(jié)構(gòu)TiAlSiN基多元涂層是今后研究的重要方向之一。此外,還提出了通過基體前處理和涂層后處理增強TiAlSiN涂層韌性和層基結(jié)合強度的發(fā)展方向。
[Abstract]:With the development of cutting technology in the direction of high speed, high efficiency, high precision, green and intelligence, cutting has put forward higher requirements for the performance of cutting tools and coatings. The quaternary hard coatings, represented by TiAlSiN coatings, have developed rapidly. The preparation process, structure and properties of monolayer TiAlSiN nanocomposite coatings were reviewed. According to the problems of low toughness and low bonding strength of TiAlSiN monolayer coatings, the necessity of studying the modification of TiAlSiN coatings was put forward. The preparation process, structure and properties of structural modification, composition modification and combination modification of TiAlSiN coatings are reviewed. It is pointed out that the transverse interlayer interface in nano-multilayer TiAlSiN coatings has a good hindering effect on the diffusion of atoms. The oxidation resistance of the coating is improved and the mechanical properties such as hardness of the coating are improved or decreased by the factors of the modulation layer composition and the modulation period of the multilayer structure. In this paper, the effect of alloying elements, such as Cu / Cu / Cr / V, on TiAlSiN coating is introduced. The main function of C element in the coating is to enhance the bonding between the coating and the substrate, and the hardness of the coating is reduced to some extent. It is put forward that it is one of the important research directions in the future to maximize the synergetic effect of adding elements and interlayer structure to obtain the best performance of nano-multilayer TiAlSiN based multicomponent coatings. In addition, the development direction of strengthening the toughness and bonding strength of TiAlSiN coating by pre-treatment and post-treatment was put forward.
【作者單位】: 成都真銳科技涂層有限公司;四川大學制造科學與工程學院;四川大學分析測試中心;
【基金】:國家科技重大專項(2015ZX04005004)~~
【分類號】:TG174.4
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本文編號:1922753
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