溫度對(duì)溴化鋰溶液中Ti-6Al-4V初期空蝕行為的影響
發(fā)布時(shí)間:2018-01-20 03:24
本文關(guān)鍵詞: Ti-Al-V合金 溴化鋰溶液 溫度 空蝕 影響機(jī)理 出處:《中國(guó)有色金屬學(xué)報(bào)》2017年07期 論文類型:期刊論文
【摘要】:采用三維視頻顯微鏡、粗糙度輪廓儀和電化學(xué)測(cè)試研究溴化鋰溶液中不同溫度條件下Ti-6Al-4V微觀空蝕形貌、粗糙度以及電化學(xué)腐蝕行為,探討溫度對(duì)空蝕的影響機(jī)理。結(jié)果表明:溫度的影響隨空蝕時(shí)間增加不斷加強(qiáng),240 min時(shí)最為顯著,之后影響減弱并趨于穩(wěn)定。溫度升高,空泡潰滅產(chǎn)生的微射流沖擊強(qiáng)度增大,使表面鈍化膜更易被破壞,同時(shí)腐蝕作用加速了點(diǎn)蝕形成,導(dǎo)致表面局部應(yīng)力集中和更多電化學(xué)電池的產(chǎn)生,從而促進(jìn)了力學(xué)和腐蝕因素,兩者的協(xié)同作用加速了空蝕破壞。空蝕破壞程度在溫度55℃時(shí)達(dá)到最大值,繼續(xù)升高溫度,腐蝕因素仍被促進(jìn),但微射流對(duì)表面的沖擊強(qiáng)度減弱,對(duì)表面鈍化膜的破壞作用降低,由于力學(xué)因素在空蝕中占據(jù)主導(dǎo)地位,因此使空蝕速率得到減緩。
[Abstract]:The micro-cavitation morphology, roughness and electrochemical corrosion behavior of Ti-6Al-4V at different temperatures in lithium bromide solution were investigated by three-dimensional video microscope, roughness profiler and electrochemical measurement. The effect of temperature on cavitation erosion is discussed. The results show that the effect of temperature on cavitation corrosion is the most obvious with the increase of cavitation time, and then decreases and tends to be stable. The impact strength of micro jet caused by bubble collapse increases, which makes the surface passivation film more easily destroyed. At the same time, corrosion accelerates the formation of pitting, resulting in local stress concentration on the surface and the production of more electrochemical cells. Thus the mechanical and corrosion factors are promoted, and the synergistic effect of the two factors accelerates the cavitation damage. The cavitation damage degree reaches the maximum at 55 鈩,
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