【摘要】：化學(xué)合成類制藥高環(huán)境污染不僅體現(xiàn)在水環(huán)境污染方面,更加突出體現(xiàn)在大氣污染方面�；瘜W(xué)制藥涉及原輔料眾多,大部分為有機(jī)溶劑,且含有一些“致畸、致癌、致突變”物質(zhì),若得不到妥善的處理容易造成水體和大氣污染,尤其是廢氣排放引起的惡臭問(wèn)題,是群眾重點(diǎn)投訴的大氣環(huán)境問(wèn)題。隨著國(guó)家《重點(diǎn)區(qū)域大氣污染防治“十二五”規(guī)劃》(浙環(huán)函〔2011〕478號(hào))和浙江省大氣復(fù)合污染防治實(shí)施方案的開(kāi)展和落實(shí),化學(xué)合成類制藥行業(yè)大氣污染防治工作已被提上日程。目前化學(xué)合成類制藥工業(yè)大氣污染的監(jiān)管主要沿用的是《大氣污染物綜合排放標(biāo)準(zhǔn)》和《惡臭污染物排放標(biāo)準(zhǔn)》,然而前述兩項(xiàng)標(biāo)準(zhǔn)發(fā)布時(shí)間過(guò)早并且均未能對(duì)化學(xué)合成類制藥工業(yè)大氣特征污染物進(jìn)行控制。本論文以此為背景展開(kāi)化學(xué)合成類制藥工業(yè)大氣污染物排放標(biāo)準(zhǔn)的相關(guān)研究。在全面深入地研究國(guó)內(nèi)外與化學(xué)合成類制藥工業(yè)相關(guān)的標(biāo)準(zhǔn)和技術(shù)規(guī)范的基礎(chǔ)上,根據(jù)浙江省該行業(yè)的實(shí)際生產(chǎn)工藝及廢氣污染治理技術(shù),結(jié)合實(shí)地監(jiān)測(cè)等手段,進(jìn)行污染物來(lái)源解析以及污染物排放特征分析。建議提出《化學(xué)合成類制藥工業(yè)大氣污染物排放標(biāo)準(zhǔn)》(草案),確定出該行業(yè)污染控制指標(biāo)為顆粒物、氯化氫、氨、苯、甲醛、二氯甲烷、三氯甲烷、甲醇、乙酸乙酯、丙酮、乙腈、苯系物、VOCs、臭氣濃度、其他物質(zhì)和二VA英共16項(xiàng)指標(biāo),也建議規(guī)定了相應(yīng)的排放限值。標(biāo)準(zhǔn)中現(xiàn)有企業(yè)、新建企業(yè)、特別排放和無(wú)組織排放限值具體為,顆粒物(20mg/m3、15mg/m3、10mg/m3、—)、氯化氫(20mg/m3、10mg/m3、5mg/m3、0.15mg/m3)、氨(20mg/m3、10mg/m3、5mg/m3、1.0mg/m3)、苯(2.0mg/m3、1.0mg/m3、0.5mg/m3、0.10mg/m3)、甲醛(2.0mg/m3、1.0mg/m3、0.5mg/m3、0.20mg/m3)、二氯甲烷(40mg/m3、20mg/m3、10mg/m3、1.0mg/m3)、三氯甲烷(20mg/m3、10mg/m3、5mg/m3、1.0mg/m3)、甲醇(40mg/m3、20mg/m3、10mg/m3、2.0mg/m3)、乙酸乙酯(60mg/m3、40mg/m3、20mg/m3、2.0mg/m3)、丙酮(60mg/m3、40mg/m3、20mg/m3、2.0mg/m3)、乙腈(40mg/m3、20mg/m3、10mg/m3、2.0mg/m3)、苯系物(20mg/m3、10mg/m3、5mg/m3、2.0mg/m3)、VOCs(200mg/m3、150mg/m3、100mg/m3、—)、臭氣濃度(1000mg/m3、800mg/m3、500mg/m3、20mg/m3)、其他物質(zhì)A類(2.0mg/m3、1.0mg/m3、0.5mg/m3、—)、其他物質(zhì)B類(30mg/m3、20mg/m3、10mg/m3、—)和二VA英(0.1mg/m3、0.1mg/m3、0.1mg/m3、—)。
[Abstract]:High environmental pollution of synthetic pharmacy is not only reflected in water pollution, but also in air pollution. Chemical pharmaceuticals involve many raw and auxiliary materials, most of which are organic solvents, and contain some "teratogenic, carcinogenic, mutagenic" substances. If not properly treated, they will easily cause water and air pollution, especially the stench caused by exhaust gas emissions. It is the atmospheric environmental problem that the masses mainly complains. With the implementation of the 12th Five-Year Plan for the Prevention of Air pollution in key regions (Zhejiang Huan-Quan (2011) 478) and the implementation of the Program for the Prevention and Control of Air pollution in Zhejiang Province, The prevention and control of air pollution in synthetic pharmaceutical industry has been put on the agenda. At present, the supervision of air pollution in the pharmaceutical industry of chemical synthesis mainly adopts the Integrated Emission Standards of Atmospheric pollutants and the discharge Standards of odorous pollutants. Both standards, however, were issued too early and failed to control the chemical synthetic pharmaceutical industry's atmospheric characteristics. Based on this background, this paper studies the emission standards of atmospheric pollutants in chemosynthetic pharmaceutical industry. On the basis of a comprehensive and in-depth study of domestic and foreign standards and technical specifications related to the chemical synthetic pharmaceutical industry, according to the actual production process and waste gas pollution control technology of this industry in Zhejiang Province, combined with field monitoring and other means, To analyze the source of pollutants and the characteristics of pollutant discharge. It is suggested that the standard for the emission of atmospheric pollutants from chemosynthetic pharmaceutical industry be put forward (draft), and that the pollution control indexes of this industry be determined as particulate matter, hydrogen chloride, ammonia, benzene, formaldehyde, dichloromethane, trichloromethane, methanol, ethyl acetate, etc. Acetone, acetonitrile, benzenes, VOCs, ozone concentration, other substances and two VA were 16 indexes, and the corresponding emission limits were suggested. The specific emission limits for existing enterprises, new businesses, special emissions, and unorganized emissions in the standard are: particulate matter (20 mg / m3 / m3 15mg / m3n = 10 mg / m3n-), hydrogen chloride (20mg / m3n = 10 mg / m3 / m3), ammonia (20 mg / m310mg / m3 / 5mgr / m3mm3), ammonia (20mg / m310mgr / m3m3m3m3m3mm3). Benzene (2.0 mg / m3, 1.0 mg / m3, 0.5 mg / m3 = 0.10 mg / m3), formaldehyde (2.0 mg / m3, 1.0 mg / m3, 0.5 mg / m3or 0.20 mg / m3), dichloromethane (40 mg / m320mg / m3+ m310mg / m31.0mg/ m3), Chloromethane (20mg / m310mgP / m3n), methanol (40mg / m3n = 20mg / m310mg / m3), ethyl acetate (60mg / m340mg / m320mg / m32.0mg/ m3), acetone (60mg / m340mg/ m3rm3o20 mg/ m3), acetone (60mg/ m340mgrm3m3m3m3rm3), methylene chloride (40mg / m310mg / m3), ethyl acetate (60mg / m340mg / m320mg / m3t / m3), acetone (60mg / m340mg / m3rm3m3m3mrm3), Acetonitrile (40 mg / m3, 20 mg / m3, 10 mg / m3, 2.0 mg / m3), benzene (20 mg / m310 mg / m3 + 5 mg / m3, 2.0 mg / m3), VOCs (200mgm3150mgr / m3100mgm3m3-), ozone concentration (1000mgm3800mgrm3500mgm3m3m3mgm3 / m3), Other substances A (2.0 mg / m3 1.0 mg / m3N 0.5 mg / m3), other substance B (30 mg / m3n 20 mg / m3N 10 mg / m3) and 2 VA UK (0.1 mg / m3N 0.1 mg / m30.1 mg / m3m3-).
【學(xué)位授予單位】：浙江工業(yè)大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2015
【分類號(hào)】：X787

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