烏魯木齊市周邊地區(qū)土壤中多環(huán)芳烴的含量及來源
發(fā)布時間:2018-06-24 17:36
本文選題:PAHs + 土壤。 參考:《土壤》2016年06期
【摘要】:在烏魯木齊市周邊,從烏拉泊到水西溝按不同距離與深度進行土壤樣品采集,采用索氏提取法與層析凈化法進行預(yù)處理,高效液相色譜法測定土壤中16種多環(huán)芳烴(PAHs)的含量,并對PAHs進行對比分析、污染評價和來源分析的相關(guān)研究。結(jié)果表明:總PAHs平均濃度為998.23(306.94~3 652.16)ng/g,污染程度差異不大,處中度污染水平但更接近嚴重污染水平;16種PAHs的最低檢測限為0.20~0.80 ng/g;一些采樣點的表層土壤中苯并[a]芘的含量高于土壤質(zhì)量控制標準。不同層次土壤PAHs的污染程度有所不同,其順序為表層中層下層;高分子量(4~6環(huán))PAHs占據(jù)了總含量的84.1%,低分子量(2~3環(huán))PAHs占據(jù)15.9%,得出在烏魯木齊市周邊土壤中PAHs的重要來源是汽車排放,同時煤燃燒排放的貢獻也很大。
[Abstract]:Around Urumqi, soil samples were collected from Urapor to Shuixigou at different distances and depths. The contents of 16 polycyclic aromatic hydrocarbons (PAHs) in soil were determined by high performance liquid chromatography (HPLC) after pretreatment by Soxhlet extraction and chromatography. The comparative analysis, pollution assessment and source analysis of PAHs were carried out. The results showed that the average concentration of total PAHs was 998.23 (306.94 鹵3 652.16) ng / g, and the pollution degree was not different. The lowest detection limit of 16 PAHs was 0.20 ~ 0.80 ng / g, and the content of benzo [a] pyrene in topsoil of some sampling sites was higher than that of soil quality control standard. The pollution degree of PAHs in different layers was different, and the order of PAHs was the surface layer and the lower layer. High molecular weight (4 ~ 6 ring) PAHs occupied 84.1% of the total content, and low molecular weight (2 ~ 3 ring) PAHs occupied 15.9%. It was concluded that the important source of PAHs in the soil around Urumqi was vehicle emissions, and the contribution of coal combustion emissions was also very great.
【作者單位】: 新疆農(nóng)業(yè)大學(xué)草業(yè)與環(huán)境科學(xué)學(xué)院;
【基金】:國家自然科學(xué)基金項目(21167017;20567028)資助
【分類號】:X53
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本文編號:2062395
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