【摘要】：1.本文首先對(duì)一種新型有機(jī)共軛聚合物F1/4F8BT和其與PFO共混薄膜的光學(xué)特性進(jìn)行了深入詳細(xì)的研究。這種新型的黃綠光聚合物材料F1/4F8BT與PFO共混后有著優(yōu)異的光學(xué)增益特性。從實(shí)驗(yàn)表征結(jié)果來(lái)看,在PFO:F8BT共混薄膜中,由于F8BT的自發(fā)發(fā)射與PFO極化子對(duì)的競(jìng)爭(zhēng)關(guān)系,薄膜有著較高的自發(fā)發(fā)射放大(Amplified Spontaneous Emission,ASE)閾值;而F1/4F8BT與PFO共混薄膜的ASE閾值較F8BT薄膜降低了30%,而且其光學(xué)凈增益增加了50%。這樣我們就研發(fā)出一種比市面上商業(yè)化銷售的黃綠光發(fā)光材料發(fā)光性能更強(qiáng),生產(chǎn)方法及成本幾乎相同的新型黃綠光發(fā)光聚合物,其市場(chǎng)化前景有很大潛力。2.然后本文對(duì)當(dāng)今光伏領(lǐng)域最熱門的鈣鈦礦型材料進(jìn)行了光學(xué)性能的表征,發(fā)現(xiàn)其擁有出色的自發(fā)發(fā)射放大特性,可以通過(guò)改變鹵族元素調(diào)整其發(fā)射光譜至黃綠光波段。并通過(guò)掃描電子顯微鏡來(lái)觀測(cè)并研究鈣鈦礦薄膜器件的表面形貌。3.由于鈣鈦礦材料優(yōu)良的半導(dǎo)體特性,我們將其應(yīng)用到有機(jī)無(wú)機(jī)雜化半導(dǎo)體激光器研制中,并創(chuàng)造性地在分布反饋式(Distributed Feed Back,DFB)激光器結(jié)構(gòu)中引入波導(dǎo)元件,有益于降低激光器的激發(fā)閾值。利用專業(yè)的光學(xué)仿真軟件對(duì)激光器件結(jié)構(gòu)進(jìn)行設(shè)計(jì),對(duì)整個(gè)器件光學(xué)性能進(jìn)行模擬仿真,得到了激光輸出結(jié)果。對(duì)于實(shí)驗(yàn)室制備鈣鈦礦電泵浦激光器,建議了器件結(jié)構(gòu)和制備方法,為該領(lǐng)域研究人員繼續(xù)進(jìn)行探索提供了參考。本文針對(duì)聚合物激光材料設(shè)計(jì)、鈣鈦礦材料光增益性能的初步研究,以及激光器件光學(xué)參數(shù)的仿真模擬,為研究新型更有效的有機(jī)和有機(jī)/無(wú)機(jī)雜化激光器件拓展了新的思路。
[Abstract]:1. In this paper, the optical properties of a new organic conjugated polymer F1/4F8BT and its blend films with PFO were studied in detail. This new yellow-green photopolymer material F1/4F8BT and PFO have excellent optical gain characteristics. The experimental results show that in PFO:F8BT blend films, due to the competitive relationship between F8BT spontaneous emission and PFO polaron pair, the film has a higher spontaneous emission amplification (Amplified Spontaneous Emission,ASE threshold, while the ASE threshold of F1/4F8BT and PFO blend films is 30% lower than that of F8BT films, and its optical net gain is increased by 50%. In this way, we have developed a new type of yellow-green luminous polymer, which has stronger luminous properties and almost the same production method and cost than the commercial yellow-green luminous material sold on the market, and its market-oriented prospect has great potential. 2. Then, the optical properties of the most popular perovskite materials in photovoltaic field are characterized in this paper. It is found that the perovskite materials have excellent spontaneous emission amplification characteristics, and the emission spectrum can be adjusted to the yellow and green band by changing the halogen group elements. The surface morphology of perovskite thin film devices was observed and studied by scanning electron microscope. Because of the excellent semiconductor properties of perovskite materials, we apply it to the development of organic-inorganic hybrid semiconductor lasers, and creatively introduce waveguide elements into the distributed feedback (Distributed Feed Back,DFB) laser structure, which is beneficial to reduce the excitation threshold of the laser. The structure of the laser device is designed by using the professional optical simulation software, and the optical performance of the whole device is simulated, and the laser output results are obtained. For the preparation of perovskite electric pump laser in laboratory, the device structure and fabrication method are suggested, which provides a reference for researchers in this field to continue to explore. In this paper, the design of polymer laser materials, the preliminary study of optical gain performance of perovskite materials and the simulation of optical parameters of laser devices expand a new idea for the study of new and more effective organic and organic / inorganic hybrid laser devices.
【學(xué)位授予單位】：南京郵電大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2017
【分類號(hào)】：TN304;TN248

【相似文獻(xiàn)】

中國(guó)期刊全文數(shù)據(jù)庫(kù) 前10條

1 梅海林;唐立丹;王冰;馮嘉恒;;鈣鈦礦型太陽(yáng)能電池的研究進(jìn)展[J];遼寧工業(yè)大學(xué)學(xué)報(bào)(自然科學(xué)版);2016年01期

2 孟淼飛;馬錫英;;鈣鈦礦型太陽(yáng)電池的研究進(jìn)展[J];微納電子技術(shù);2015年08期

3 楊婭婷;段少勇;姜恒;宮紅;;鈣鈦礦型堿金屬鉭酸鹽中A位離子變換的原因[J];鹽業(yè)與化工;2014年02期

4 陳婷;鄭惠丹;王品;苗承榮;劉佳雯;;鈣鈦礦型光催化劑的合成、改性摻雜與負(fù)載技術(shù)的研究進(jìn)展[J];化學(xué)工程師;2008年08期

5 李中秋;侯桂芹;張文麗;;鈣鈦礦型固體電解質(zhì)材料的發(fā)展現(xiàn)狀[J];河北理工學(xué)院學(xué)報(bào);2006年01期

6 李中秋,侯桂芹,張文麗,仉小猛;鈣鈦礦型固體電解質(zhì)材料的研究進(jìn)展[J];山東陶瓷;2005年04期

7 王道,王蘇婭,李琬;鈣鈦礦型稀土催化劑負(fù)載方法的研究[J];環(huán)境化學(xué);1988年01期

8 彭高聰,楊汝棟,齊玉蘭,劉建民;變價(jià)稀土鈣鈦礦型化合物在稀土分離中的應(yīng)用——氧化還原法分離鐠釹[J];稀土;1988年02期

9 溫元?jiǎng)P,柳宏波,李鵬鴿,聶圣哲,周栓虎;鈣鈦礦型氧化物超導(dǎo)體的模式識(shí)別研究[J];硅酸鹽學(xué)報(bào);1989年01期

10 張燕妮 ,楊宏秀 ,馬忠干;鈣鈦礦型La_(1-X)Sr_X Mn_(1-Y) Cu_Y O_3系對(duì)CO催化性能及其與表面過(guò)剩氧量的關(guān)系[J];蘭州大學(xué)學(xué)報(bào);1989年03期

中國(guó)重要會(huì)議論文全文數(shù)據(jù)庫(kù) 前10條

1 李嵩;張丹丹;孫俊才;;新型類鈣鈦礦型陰極材料的合成與電性能表征[A];第二十八屆全國(guó)化學(xué)與物理電源學(xué)術(shù)年會(huì)論文集[C];2009年

2 申旭東;殷云宇;周龍;龍有文;;鈣鈦礦型材料BiMn_3Mn_2Ni_2O_(12)的高溫高壓合成及物性研究[A];第十八屆中國(guó)高壓科學(xué)學(xué)術(shù)會(huì)議縮編文集[C];2016年

3 張慧敏;胡瑞生;白雅琴;蔡麗;蘇海全;;單雙鈣鈦礦型甲烷燃燒催化劑制備方法及應(yīng)用進(jìn)展[A];中國(guó)化工學(xué)會(huì)2009年年會(huì)暨第三屆全國(guó)石油和化工行業(yè)節(jié)能節(jié)水減排技術(shù)論壇會(huì)議論文集（上）[C];2009年

4 肖爽;楊世和;;Interface and Electrode Engineering for Low-cost and High-performance Perovskite Solar Cells[A];第五屆新型太陽(yáng)能電池學(xué)術(shù)研討會(huì)摘要集（鈣鈦礦太陽(yáng)能電池篇）[C];2018年

5 陳駿;鄧金俠;于然波;邢獻(xiàn)然;;鈣鈦礦型鉛基化合物結(jié)構(gòu)、負(fù)熱膨脹及性能[A];中國(guó)化學(xué)會(huì)第29屆學(xué)術(shù)年會(huì)摘要集——第05分會(huì)：無(wú)機(jī)化學(xué)[C];2014年

6 張煥;薛冬峰;;ABO_3鈣鈦礦型化合物的結(jié)構(gòu)穩(wěn)定性和形成性規(guī)律[A];《硅酸鹽學(xué)報(bào)》創(chuàng)刊50周年暨中國(guó)硅酸鹽學(xué)會(huì)2007年學(xué)術(shù)年會(huì)論文摘要集[C];2007年

7 蘇杭;李靜;肖俊彥;;基于碳膜電極的柔性鈣鈦礦電池[A];第五屆新型太陽(yáng)能電池學(xué)術(shù)研討會(huì)摘要集（鈣鈦礦太陽(yáng)能電池篇）[C];2018年

8 劉曉娟;黃碧純;付名利;葉代啟;吳軍良;齊少英;張棲;梁紅;;載體浸漬改性對(duì)鈣鈦礦型催化劑催化碳煙燃燒性能的影響[A];第六屆全國(guó)環(huán)境催化與環(huán)境材料學(xué)術(shù)會(huì)議論文集[C];2009年

9 宋銳;楊銘;袁宏明;馮守華;;B位摻雜Fe的鈣鈦礦型錳酸鹽的水熱合成[A];中國(guó)化學(xué)會(huì)第26屆學(xué)術(shù)年會(huì)無(wú)機(jī)與配位化學(xué)分會(huì)場(chǎng)論文集[C];2008年

10 呂宜t，

本文編號(hào)：2509348