本論文從以下方面入手,探索提高有機(jī)太陽能電池有效性和可持續(xù)性的方法,即溶液處理的界面材料,活性層組分的改變,單結(jié)傳統(tǒng)和倒置結(jié)構(gòu)。本論文的主要內(nèi)容如下:陰極修飾層（CBL）的功函數(shù)極大地影響有機(jī)光伏器件,特別是Voc,并且可以通過修飾層和活性層之間的歐姆接觸來實(shí)現(xiàn)性能。Hf（acac）4和Ta-OMe是陰極修飾層,可以由在室溫下簡(jiǎn)單地將可溶性Hf（acac）4和Ta-OMe旋涂在光敏層上而不需要任何其他后處理來制備。該方法簡(jiǎn)單和容易,Hf（acac）4和Ta-OMe插入Al 陽極和活性層之間,作為有機(jī)BHJ太陽能電池的陽極修飾層。當(dāng)用Hf（acac）4和Ta-OMe代替?zhèn)鹘y(tǒng)的Ca/Al作為有機(jī)太陽能電池中的負(fù)極時(shí),可以顯著提高短路電流,并且同時(shí)減小串聯(lián)電阻。當(dāng)Hf（acac）4和Ta-OMe陰極用于具有P3HT:PCBM作為光活性層的SC中時(shí),在標(biāo)準(zhǔn)照射條件（AM 1.5G,100mW/cm 2）下測(cè)量的光電轉(zhuǎn)換效率（PCE）為3.89%,這顯著高于在相同條件下使用Ca/Al陰極的太陽能電池的PCE超過2.04%。有機(jī)光伏太陽能電池屬于光活性材料的光吸收,另外還取決于相對(duì)于活性層的布置的... 

【文章來源】：華北電力大學(xué)(北京)北京市 211工程院校 教育部直屬院校

【文章頁數(shù)】：92 頁

【學(xué)位級(jí)別】：博士

【文章目錄】：
Abstract
摘要
List of symbols and Abbreviations
Chapter 1 Introduction
    1.1 Organic Solar Cellslntroduction
        1.1.1 The Generation and Classification of Photovoltaic Solar Cells
        1.1.2 Inorganic Solar Cells
        1.1.3 Hybrid Solar cells
        1.1.4 Organic Solar Cells
    1.2 Basic Operation Principle and Electrical Characteristics of PVs
        1.2.1 The Basic Operation of Organic Solar Cells
        1.2.2 Electrical Characteristics of Photovoltaics
    1.3 Motivation and Current Work
    1.4 Objectives
    1.5 Methodology
    1.6 Structureof thesis
Chapter 2 Influence of the Presence of an Electron TransportLayer on Characteristics of Organic Photovoltaic Cells based on Al,Ca/Al,Ta-OMe/Al and Hf(acac)_4/Al
    2.1 Introduction
    2.2 Experimental Section
        2.2.1 Materials and Instrumentation
        2.2.2 Device Fabrication
        2.2.3 Characterization of Device
    2.3 Results and Discussion
    Conclusion
Chapter 3 Comparative on Organic Solar Cells with Different Active Layer on Bulk heterojunction
    3.1 Introduction
    3.2 Experimental Section
        3.2.1 Materials and Instrumentation
        3.2.2 Device Fabrication
        3.2.3 Device Characterization
    3.3 Results and Discussion
    Conclusion
Chapter 4 Inverted Non-fullerene Polymer Solar Cells with the TIPD modified cathode buffer layer
    4.1 Introduction
    4.2 Experimental Section
        4.2.1 Materials and Instrumentation
        4.2.2 Device Fabrication
        4.2.3 Device Characterization
    4.3 Results and Discussion
    Conclusion
Chapter 5 Conclusions
References
List of my publication during the PhD study
Acknowledgement
About the author


【參考文獻(xiàn)】：
期刊論文
[1]Effect of ZnO Electrodeposited on Carbon Film and Decorated with Metal Nanoparticles for Solar Hydrogen Production[J]. Young Kwang Kim,Hye-Jin Seo,Soonhyun Kim,Sung-Ho Hwang,Hyunwoong Park,Sang Kyoo Lim.  Journal of Materials Science & Technology. 2016(10)



本文編號(hào)：3278923