固體氧化物高溫電解池電極材料電化學(xué)特性研究
發(fā)布時(shí)間:2021-03-23 22:35
固體氧化物電池可以提供清潔能源,避免碳排放,是氫和電力生產(chǎn)的未來(lái)。它們?cè)诟邷毓ぷ鳁l件下(600℃至800℃)效率很高,可以使用的燃料靈活多樣。固體氧化物電池根據(jù)工作模式分為兩類:以提供電力為目的的固體氧化物燃料電池和以氫氣為產(chǎn)物的固體氧化物電解池。風(fēng)能和太陽(yáng)能等其他可再生能源與固體氧化物電池相結(jié)合提供可持續(xù)的清潔能源?蒲腥藛T對(duì)固體氧化物電池進(jìn)行了大量研究,包括:(a)降低工作溫度來(lái)避免材料退化問(wèn)題,(b)開發(fā)新的廉價(jià)且易于加工的材料,(c)固體氧化物電池技術(shù)商業(yè)化以滿足不同應(yīng)用需求,(d)氫能經(jīng)濟(jì)和儲(chǔ)存問(wèn)題等。氫和合成氣是一種價(jià)值很高的清潔能源,具有廣泛的應(yīng)用前景。使用固體氧化物電解池高溫電解水蒸汽和二氧化碳是一種有效的氫氣或合成氣生產(chǎn)方法。本文將從以下幾個(gè)方面對(duì)固體氧化物電池研究進(jìn)行闡述:(a)固體氧化物電池技術(shù)背景和意義;(b)固體氧化物電池商業(yè)化的研究進(jìn)展和難點(diǎn);(c)固體氧化物燃料電池材料的最新進(jìn)展和電化學(xué)特性的預(yù)測(cè);最后,總結(jié)并展望。固體氧化物電解池高溫電解水和二氧化碳制氫的高效性和高品質(zhì)已經(jīng)得到充分證實(shí)。然而,固體氧化物電池技術(shù)的商業(yè)化還面臨許多問(wèn)題需要解決。如,材料分離...
【文章來(lái)源】:中國(guó)科學(xué)技術(shù)大學(xué)安徽省 211工程院校 985工程院校
【文章頁(yè)數(shù)】:76 頁(yè)
【學(xué)位級(jí)別】:碩士
【文章目錄】:
摘要
ABSTRACT
NOMENCLATURE
CHAPTER 01: INTRODUCTION
1.1 Background
1.2 Research Status
1.3 Significance
1.4 Research Challenges and Objective
1.5 Thesis Layout
CHAPTER 02: RESEARCH CHALLENGES FORCOMMERCIALIZATION OF SOLID OXIDE CELLS
2.1 Introduction
2.2 Technological Advancement
2O/CO2 co-electrolysis in a SOEC"> 2.2.1 High-temperature H2O/CO2 co-electrolysis in a SOEC
2O/CO2 Reduction Reaction Mechanisms in SOEC"> 2.2.2 H2O/CO2 Reduction Reaction Mechanisms in SOEC
2.3 Performance degradation
2.4 Fabrication of Solid Oxide Cells
2.4.1 Fabrication cost
2.4.2 Basic Fabrication Techniques
2.5 Planar and Tubular solid oxide cells
2.6 Summary and future directions
Chapter 03: ADVANCEMENT IN SOLID OXIDE CELL MATERIALS
3.1 Introduction
3.2 Key Materials for the Co-electrolysis of steam/carbon dioxide
(a) Electrode Materials and Microstructures
(b) Fuel electrode materials
(c) Oxygen electrode materials
3.2.1 Basic electrochemical properties of MIECs and its importance
3.3 Determination of Electrochemical Kinetic Properties for MIECs
3.3.1 Synthesizing modeling and inverse algorithm
3.3.1.1 Coupled modeling of multi physical-chemical processes in the materialand the surrounding atmosphere
3.3.1.2 Inverse algorithm
3.3.2 Results and discussion
3.4 Summary and Future Directions
CONCLUSION
REFERENCES
AKNOWLEDGEMENT
LIST OF PUBLICATION
【參考文獻(xiàn)】:
期刊論文
[1]Detrimental phase evolution triggered by Ni in perovskite-type cathodes for CO2 electroreduction[J]. Shiqing Hu,Lixiao Zhang,Huanying Liu,Wenping Li,Zhongwei Cao,Lili Cai,Yue Zhu,Xuefeng Zhu,Weishen Yang. Journal of Energy Chemistry. 2019(09)
[2]Improving the performance of solid oxide electrolysis cell with gold nanoparticles-modified LSM-YSZ anode[J]. Yuefeng Song,Xiaomin Zhang,Yingjie Zhou,Houfu Lv,Qingxue Liu,Weicheng Feng,Guoxiong Wang,Xinhe Bao. Journal of Energy Chemistry. 2019(08)
本文編號(hào):3096539
【文章來(lái)源】:中國(guó)科學(xué)技術(shù)大學(xué)安徽省 211工程院校 985工程院校
【文章頁(yè)數(shù)】:76 頁(yè)
【學(xué)位級(jí)別】:碩士
【文章目錄】:
摘要
ABSTRACT
NOMENCLATURE
CHAPTER 01: INTRODUCTION
1.1 Background
1.2 Research Status
1.3 Significance
1.4 Research Challenges and Objective
1.5 Thesis Layout
CHAPTER 02: RESEARCH CHALLENGES FORCOMMERCIALIZATION OF SOLID OXIDE CELLS
2.1 Introduction
2.2 Technological Advancement
2O/CO2 co-electrolysis in a SOEC"> 2.2.1 High-temperature H2O/CO2 co-electrolysis in a SOEC
2O/CO2 Reduction Reaction Mechanisms in SOEC"> 2.2.2 H2O/CO2 Reduction Reaction Mechanisms in SOEC
2.3 Performance degradation
2.4 Fabrication of Solid Oxide Cells
2.4.1 Fabrication cost
2.4.2 Basic Fabrication Techniques
2.5 Planar and Tubular solid oxide cells
2.6 Summary and future directions
Chapter 03: ADVANCEMENT IN SOLID OXIDE CELL MATERIALS
3.1 Introduction
3.2 Key Materials for the Co-electrolysis of steam/carbon dioxide
(a) Electrode Materials and Microstructures
(b) Fuel electrode materials
(c) Oxygen electrode materials
3.2.1 Basic electrochemical properties of MIECs and its importance
3.3 Determination of Electrochemical Kinetic Properties for MIECs
3.3.1 Synthesizing modeling and inverse algorithm
3.3.1.1 Coupled modeling of multi physical-chemical processes in the materialand the surrounding atmosphere
3.3.1.2 Inverse algorithm
3.3.2 Results and discussion
3.4 Summary and Future Directions
CONCLUSION
REFERENCES
AKNOWLEDGEMENT
LIST OF PUBLICATION
【參考文獻(xiàn)】:
期刊論文
[1]Detrimental phase evolution triggered by Ni in perovskite-type cathodes for CO2 electroreduction[J]. Shiqing Hu,Lixiao Zhang,Huanying Liu,Wenping Li,Zhongwei Cao,Lili Cai,Yue Zhu,Xuefeng Zhu,Weishen Yang. Journal of Energy Chemistry. 2019(09)
[2]Improving the performance of solid oxide electrolysis cell with gold nanoparticles-modified LSM-YSZ anode[J]. Yuefeng Song,Xiaomin Zhang,Yingjie Zhou,Houfu Lv,Qingxue Liu,Weicheng Feng,Guoxiong Wang,Xinhe Bao. Journal of Energy Chemistry. 2019(08)
本文編號(hào):3096539
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