高溫蒸汽環(huán)境對電站鍋爐管材料應(yīng)力腐蝕裂紋擴(kuò)展影響研究
發(fā)布時間:2018-11-12 17:47
【摘要】:金屬材料高溫下的性能是限制先進(jìn)超(超)臨界機(jī)組發(fā)展的關(guān)鍵問題,其中鍋爐管材料在極端高溫高壓超臨界水環(huán)境中的應(yīng)力腐蝕開裂問題尤為關(guān)鍵。在極端惡劣工況下,一旦結(jié)構(gòu)材料發(fā)生開裂問題就會導(dǎo)致嚴(yán)重的安全事故,直接影響發(fā)電機(jī)組的安全可靠運(yùn)行。因此,著手研究鍋爐管材料在高溫蒸汽環(huán)境下應(yīng)力腐蝕裂紋裂紋擴(kuò)展的影響機(jī)理十分必要。論文對鎳基合金Inconel 625在700℃、725℃、750℃下,溶氧量0-8000ppb高溫蒸汽環(huán)境進(jìn)行了兩組應(yīng)力腐蝕裂紋擴(kuò)展試驗研究,采用恒應(yīng)力強(qiáng)度因子力學(xué)加載,并利用直流電位降法(DCPD)對開裂速率進(jìn)行在線監(jiān)測。實驗結(jié)束后將試樣拉斷,利用掃描電鏡SEM觀察斷口微觀形貌。實驗結(jié)果表明,鎳基合金Inconel 625試樣斷口均呈現(xiàn)出典型沿晶應(yīng)力腐蝕開裂形貌。溫度升高、溶解氧含量增大均加速了裂紋擴(kuò)展的進(jìn)程,溶氧量小于4000ppb時,裂紋擴(kuò)展速率變化較為緩慢;當(dāng)溶氧量從4000ppb增加到8000ppb時,裂紋擴(kuò)展速率急速上升。高溫蒸汽中試樣的裂紋擴(kuò)展速率略高于高溫空氣,并且在溫度越高的情況下,蒸汽環(huán)境相比于空氣環(huán)境中裂紋擴(kuò)展速率的倍數(shù)越小在裂尖應(yīng)變理論基礎(chǔ)上,以高溫氧化作為裂紋擴(kuò)展的控制因素之一,對鎳基合金Inconel 625裂紋CGR進(jìn)行模型推導(dǎo),分析了不同模型中材料裂尖應(yīng)變的敏感度。并在700℃、750℃空氣、蒸汽條件下,對材料裂紋擴(kuò)展速率進(jìn)行計算。發(fā)現(xiàn)溫度和介質(zhì)環(huán)境均加速了裂紋擴(kuò)展的進(jìn)程。同時,將實驗結(jié)果與理論計算結(jié)果對比分析,發(fā)現(xiàn)基于GZH模型下實驗數(shù)據(jù)點(diǎn)很好地貼合理論曲線,并且不同的溫度條件下,同種材料裂紋尖端處的特征長度r0均存在不同的最佳值。
[Abstract]:The performance of metal materials at high temperature is a key problem to limit the development of advanced supercritical units, especially the stress corrosion cracking of boiler tube materials in extreme high temperature and high pressure supercritical water environment. Under extremely bad working conditions, once structural materials crack, it will lead to serious safety accidents, which will directly affect the safe and reliable operation of generator sets. Therefore, it is necessary to study the mechanism of stress-corrosion crack propagation of boiler tube materials under high temperature steam environment. In this paper, two groups of stress corrosion crack propagation experiments of nickel base alloy Inconel 625 at 700 鈩,
本文編號:2327773
[Abstract]:The performance of metal materials at high temperature is a key problem to limit the development of advanced supercritical units, especially the stress corrosion cracking of boiler tube materials in extreme high temperature and high pressure supercritical water environment. Under extremely bad working conditions, once structural materials crack, it will lead to serious safety accidents, which will directly affect the safe and reliable operation of generator sets. Therefore, it is necessary to study the mechanism of stress-corrosion crack propagation of boiler tube materials under high temperature steam environment. In this paper, two groups of stress corrosion crack propagation experiments of nickel base alloy Inconel 625 at 700 鈩,
本文編號:2327773
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