先進功能分子體系的設(shè)計與組裝——從低維到多維
發(fā)布時間：2018-11-06 16:21
【摘要】：在設(shè)計、合成功能分子基元的基礎(chǔ)上,綜合考慮能量、結(jié)構(gòu)和性質(zhì)匹配的原則及小尺度下復(fù)雜的物理化學現(xiàn)象等關(guān)鍵科學問題,建立了自組裝新方法,發(fā)展了尺寸與結(jié)構(gòu)可控的分子聚集態(tài)結(jié)構(gòu)材料定向、定維自組裝技術(shù),構(gòu)建了大面積、高有序分子聚集態(tài)結(jié)構(gòu)材料.并研究了有序異質(zhì)和同質(zhì)結(jié)構(gòu)以及表界面問題,特別是界面活性、界面連接等關(guān)鍵科學問題.證明了分子聚集態(tài)材料中的性質(zhì)和性能與形貌、尺寸和維數(shù)的強烈依賴關(guān)系.從合成化學新的視角出發(fā),建立了合成碳的新同素異形體——石墨炔的新方法,并研究了石墨炔在信息技術(shù)、電子、能源、催化以及光電等領(lǐng)域的應(yīng)用.這些研究對化學、材料科學、物理學、微電子學等基礎(chǔ)科學研究以及基于這些學科的交叉研究具有重大的科學意義.
[Abstract]:Based on the design and synthesis of functional molecular units and taking into account the principles of energy, structure and property matching, and the complex physicochemical phenomena in small scale, a new self-assembly method is established. The molecular aggregate structure materials with controllable size and structure have been developed, and the structure of molecular aggregates with large area and high order has been constructed by using the technique of orientation and fixed dimension self-assembly. Some key scientific problems, such as interface activity, interface connection and so on, are studied. The strong dependence of properties and properties on morphology, size and dimension of molecular aggregates is proved. From a new perspective of synthetic chemistry, a new method of synthesizing carbon isomorphism, graphite acetylene, is established. The applications of graphite acetylene in information technology, electronics, energy, catalysis and photoelectricity are also studied. These studies are of great scientific significance to the basic scientific research, such as chemistry, material science, physics, microelectronics and so on, as well as the intersecting research based on these disciplines.
【作者單位】： 中國科學院化學研究所有機固體院重點實驗室北京分子科學國家實驗室;中國科學院大學;
【基金】：國家重點基礎(chǔ)研究發(fā)展計劃(編號:2016YFA0200104) 中國科學院重點項目(編號:QYZDY-SSW-SLH015)和中國科學院戰(zhàn)略性先導(dǎo)科技專項(編號:XDB12010300)資助項目
【分類號】：TB30
[Abstract]:Based on the design and synthesis of functional molecular units and taking into account the principles of energy, structure and property matching, and the complex physicochemical phenomena in small scale, a new self-assembly method is established. The molecular aggregate structure materials with controllable size and structure have been developed, and the structure of molecular aggregates with large area and high order has been constructed by using the technique of orientation and fixed dimension self-assembly. Some key scientific problems, such as interface activity, interface connection and so on, are studied. The strong dependence of properties and properties on morphology, size and dimension of molecular aggregates is proved. From a new perspective of synthetic chemistry, a new method of synthesizing carbon isomorphism, graphite acetylene, is established. The applications of graphite acetylene in information technology, electronics, energy, catalysis and photoelectricity are also studied. These studies are of great scientific significance to the basic scientific research, such as chemistry, material science, physics, microelectronics and so on, as well as the intersecting research based on these disciplines.
【作者單位】： 中國科學院化學研究所有機固體院重點實驗室北京分子科學國家實驗室;中國科學院大學;
【基金】：國家重點基礎(chǔ)研究發(fā)展計劃(編號:2016YFA0200104) 中國科學院重點項目(編號:QYZDY-SSW-SLH015)和中國科學院戰(zhàn)略性先導(dǎo)科技專項(編號:XDB12010300)資助項目
【分類號】：TB30
【相似文獻】
相關(guān)期刊論文 前10條
1 李湘洲;;自組裝材料[J];金屬世界;2006年01期
2 王秀梅;喬琳;;促血管內(nèi)皮細胞生長的功能化自組裝多肽框架材料的篩選和制備[J];中國組織工程研究與臨床康復(fù);2011年38期
3 蒙延雙;朱福良;王達健;;自組裝制備銪離子摻雜氧化鋁球形熒光顆粒[J];稀土;2008年04期
4 孫偉海;耿，
本文編號：2314813
本文鏈接：http://sikaile.net/kejilunwen/cailiaohuaxuelunwen/2314813.html
最近更新
教材專著
