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基于棉稈的離子液體溶解及其全纖維素復(fù)合材料的制備與性能研究

發(fā)布時間:2018-08-27 07:02
【摘要】:采用離子液體1-丁基-3-甲基咪唑氯鹽{[BMIM]Cl}溶解棉稈纖維(CSF)制成溶劑,將棉稈皮纖維作為增強材料與所制得的溶劑復(fù)合制備全纖維素復(fù)合材料(ACC)?疾炝藴囟取⒗w維素質(zhì)量分?jǐn)?shù)對纖維素/[BMIM]Cl體系黏度和復(fù)合材料力學(xué)性能的影響。采用偏光熱臺顯微鏡、掃描電鏡(SEM)、X射線衍射(XRD)、FT-IR對棉稈纖維的溶解及復(fù)合材料結(jié)構(gòu)進行表征。結(jié)果表明:在同一溫度下,纖維素/[BMIMI]Cl體系黏度隨著纖維素質(zhì)量分?jǐn)?shù)的增加呈現(xiàn)劇增趨勢;在同一質(zhì)量分?jǐn)?shù)下,其黏度隨著溫度的升高呈下降趨勢。當(dāng)溫度為105℃、纖維素溶液質(zhì)量分?jǐn)?shù)為8%時,全纖維素復(fù)合材料的拉伸強度達到最大值,為45.23 MPa。
[Abstract]:Using ionic liquid 1 Ding Ji 3 methyl imidazole chloride {[BMIM] Cl} to dissolve cotton stalk fiber (CSF) into solvent, cotton stalk skin fiber was used as reinforcement material and the prepared solvent was used to prepare holocellulose composite (ACC). The effects of temperature and cellulose mass fraction on the viscosity and mechanical properties of cellulose / [BMIM] Cl system were investigated. The dissolution of cotton stalk fiber and the structure of composite material were characterized by polarizing thermostat microscope and scanning electron microscope (SEM) X-ray diffraction (XRD) FT-IR. The results show that the viscosity of cellulose / [BMIMI] Cl system increases sharply with the increase of cellulose mass fraction at the same temperature, and decreases with the increase of temperature at the same mass fraction. When the temperature is 105 鈩,

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