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氧化還原電位在黃銅礦生物濕法冶金中的作用及其調(diào)控:綜述(英文)

發(fā)布時(shí)間:2022-09-30 16:14
  黃銅礦是一種重要的銅資源,但由于黃銅礦晶格能較高,溶解動(dòng)力學(xué)較低,導(dǎo)致其在濕法冶金過程中浸出效率不理想。為了解決這一問題進(jìn)行了一系列新技術(shù)的研究,包括對高效菌株的選育,抑制在礦物表面鈍化膜的生成,以及控制溶液氧化還原電位在最佳區(qū)間內(nèi)。目前,對前兩個(gè)技術(shù)的研究工作已有大量的總結(jié),而對于控制氧化還原電位這一過程的工作總結(jié)較少。本文通過研究近年來的相關(guān)工作,介紹了銅濕法冶金過程中溶液氧化還原電位的定義、作用以及對氧化還原電位的控制等相關(guān)內(nèi)容。 

【文章頁數(shù)】:16 頁

【文章目錄】:
1 Introduction
2 Definition of redox potential
3 Role of redox potential in hydrometallurgy of chalcopyrite
    3.1 Thermodynamic calculation
    3.2 Promoting formation of intermediate products
    3.3 Inhibiting formation of passivation layer
4 Maintenance of redox potential
    4.1 Using an electro-bioreactor
    4.2 Limiting oxygen concentration
    4.3 Adding different ions
    4.4 Adding chemical reagents like potassium permanganate or H2O2
    4.5 Adding ferric reductant
    4.6 Adding iron removal agent
5 Conclusions and prospect


【參考文獻(xiàn)】:
期刊論文
[1]溫度誘導(dǎo)相變對黃銅礦生物浸出的影響(英文)[J]. �?尚�,張雁生,張家明,李騰飛,王軍,覃文慶.  Transactions of Nonferrous Metals Society of China. 2019(10)
[2]Stepwise dissolution of chalcopyrite bioleaching by thermophile A.manzaensis and mesophile L. ferriphilum[J]. 顧幗華,熊先學(xué),胡可婷,李雙棵,王重慶.  Journal of Central South University. 2015(10)
[3]Bioleaching of chalcopyrite and bornite by moderately thermophilic bacteria: an emphasis on their interactions[J]. Hong-bo Zhao,Jun Wang,Xiao-wen Gan,Wen-qing Qin,Ming-hao Hu,Guan-zhou Qiu.  International Journal of Minerals Metallurgy and Materials. 2015(08)
[4]Adsorption and leaching of chalcopyrite by Sulfolobus metallicus YN24 cultured in the distinct energy sources[J]. Yu-ting Liang,Shan Zhu,Jun Wang,Chen-bing Ai,Wen-qing Qin.  International Journal of Minerals Metallurgy and Materials. 2015(06)
[5]Control of redox potential by oxygen limitation in selective bioleaching of chalcocite and pyrite[J]. Biao Wu,Jian-Kang Wen,Bo-Wei Chen,Guo-Cheng Yao,Dian-Zuo Wang.  Rare Metals. 2014(05)
[6]Comparative study on the passivation layers of copper sulphide minerals during bioleaching[J]. Kai-bin Fu 1,2),Hai Lin 1),Xiao-lan Mo 1),Han Wang 1),Hong-wei Wen 1),and Zi-long Wen 1) 1) School of Civil and Environmental Engineering,University of Science and Technology Beijing,Beijing 100083,China 2) Key Laboratory of Solid Waste Treatment and Resource Recycle(Ministry of Education),Southwest University of Science and Technology,Mianyang 621010,China.  International Journal of Minerals Metallurgy and Materials. 2012(10)



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