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酸巖表面反應(yīng)速度常數(shù)與反應(yīng)級數(shù)的解析關(guān)系

發(fā)布時(shí)間:2018-06-24 10:18

  本文選題:旋轉(zhuǎn)圓盤 + 反應(yīng)級數(shù); 參考:《鉆采工藝》2017年06期


【摘要】:文章以酸巖反應(yīng)動(dòng)力學(xué)為理論,研究了鹽酸與方解石的酸巖反應(yīng),通過理論分析,提出了反應(yīng)比表面和表面反應(yīng)密度兩個(gè)新的概念,最終得到了酸巖表面反應(yīng)中反應(yīng)速度常數(shù)與反應(yīng)級數(shù)之間的解析關(guān)系,并在此關(guān)系的基礎(chǔ)上建立了數(shù)值求解方法。同時(shí),開展了旋轉(zhuǎn)巖盤酸巖反應(yīng)實(shí)驗(yàn),采用失重法測試了鹽酸與方解石的反應(yīng)速度,并采用圖解法得到了反應(yīng)速度常數(shù)與反應(yīng)級數(shù)。通過對比,實(shí)驗(yàn)結(jié)果與理論分析得到的結(jié)果基本一致,驗(yàn)證了解析關(guān)系的正確性,研究成果為酸巖反應(yīng)模型提供了新的理論基礎(chǔ)。
[Abstract]:Based on the theory of acid rock reaction kinetics, the acid rock reaction between hydrochloric acid and calcite is studied. Through theoretical analysis, two new concepts of reaction specific surface and surface reaction density are proposed. Finally, the analytical relationship between the reaction rate constant and the reaction order in the surface reaction of acid rock is obtained, and a numerical solution method is established on the basis of the relationship. At the same time, the reaction rate of hydrochloric acid and calcite was measured by weightlessness method, and the reaction rate constant and reaction order were obtained by graphic method. By comparison, the experimental results are basically consistent with those obtained by theoretical analysis, which verifies the correctness of the analytical relationship and provides a new theoretical basis for the acid-rock reaction model.
【作者單位】: 成都理工大學(xué);中國石油勘探開發(fā)研究院;貝克休斯(中國)油田技術(shù)服務(wù)有限公司;中國石油規(guī)劃總院;
【分類號(hào)】:TE357.2
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本文編號(hào):2061194

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