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催化裂化催化劑尾氣成套處理技術的開發(fā)和應用

發(fā)布時間:2018-06-16 09:09

  本文選題:催化裂化催化劑 + 噴霧干燥。 參考:《北京化工大學》2015年碩士論文


【摘要】:催化裂化催化劑制備過程中產生的三股尾氣,都不能完全達到現行的尾氣國家排放標準。本文通過優(yōu)化焙燒尾氣治理系統(tǒng)的噴淋水量和噴淋覆蓋面積,延長尾氣在吸收塔的停留時間,改善吸收效果,在一級急冷+一級吸收工藝的基礎上,開發(fā)了一級急冷+二級吸收尾氣處理技術,該技術應用于催化裂化催化劑焙燒尾氣的治理;通過對尾氣治理技術的比選和對一級急冷+二級吸收處理技術的優(yōu)化、工業(yè)運行數據分析,確定了催化劑氣流干燥尾氣使用干式、濕式相結合的布袋除塵器+一級急冷+二級吸收的處理工藝;針對催化劑噴霧干燥尾氣進行了一級急冷+二級吸收處理技術的優(yōu)化試驗、湍沖逆噴動力波試驗和吸收水中物料回用試驗,確定了噴霧干燥尾氣使用湍沖逆噴動力波+文丘里洗滌工藝。催化裂化尾氣治理成套技術工業(yè)應用后,通過不斷優(yōu)化動改,各套尾氣系統(tǒng)都達到了長周期穩(wěn)定運行的要求,生產過程中產生的尾氣都完全達標排放,粉塵排放濃度不僅滿足≤120毫克/立方米的國家排放標準,而且達到≤30毫克/立方米的地方政府要求。其中,動力波+文丘里洗滌技術、脈沖袋式除塵器+一級急冷+二級吸收技術在其它三套催化劑裝置成功進行了推廣應用,使催化劑齊魯分公司的催化劑生產裝置的尾氣粉塵含量都達到了地方排放標準,保證了企業(yè)的正常生產和可持續(xù)發(fā)展;而且,實現了氣流干燥尾氣余熱和噴霧尾氣吸收水中物料的回收利用,提高了催化劑裝置的收率,降低了生產成本和能耗。
[Abstract]:The three streams of tail gas produced during the preparation of FCC catalyst can not fully meet the current national emission standards. In this paper, the spray water quantity and spray coverage area of roasting tail gas treatment system are optimized, the residence time of tail gas in the absorption tower is prolonged, and the absorption effect is improved. This technology was applied to the treatment of catalytic cracking catalyst roasting tail gas, and the comparison and selection of the tail gas treatment technology and the optimization of the first stage rapid cooling secondary absorption treatment technology were carried out. Based on the analysis of industrial operation data, the treatment process of first-order rapid cooling and second-order absorption of catalyst air-flow drying tail gas was determined by combining dry and wet bag dust catcher. In this paper, the optimization test of first-order and second-order absorption treatment technology for tail gas of catalyst spray drying, the dynamic wave test of turbulent backflow spray and the reuse test of absorbing water material were carried out. The spray-drying tail gas was washed by turbulent inverse spray power wave Venturi. After the industrial application of the complete set of technology for treating FCC tail gas, through continuous optimization and modification, each set of tail gas systems has met the requirements of long-term stable operation, and the tail gas produced in the production process has completely reached the standard of discharge. The dust emission concentration not only meets the national emission standard of 鈮,

本文編號:2026151

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