本文關(guān)鍵詞： 頁(yè)巖氣 容量法 重量法 等溫吸附 過(guò)剩吸附量　出處：《化工進(jìn)展》2017年05期 　論文類型：期刊論文

【摘要】：頁(yè)巖吸附氣含量是準(zhǔn)確評(píng)價(jià)頁(yè)巖含氣量和資源潛力的關(guān)鍵參數(shù),目前通常采用等溫吸附實(shí)驗(yàn)來(lái)確定。等溫吸附實(shí)驗(yàn)方法主要分為容量法和重量法,容量法是目前常用的等溫吸附實(shí)驗(yàn)方法,重量法的應(yīng)用還較少。本文通過(guò)分析兩種方法的實(shí)驗(yàn)原理,認(rèn)為容量法和重量法等溫吸附實(shí)驗(yàn)測(cè)得的吸附量均為過(guò)剩吸附量,絕對(duì)吸附量并不能通過(guò)實(shí)驗(yàn)直接測(cè)得,并建立了過(guò)剩吸附量與絕對(duì)吸附量的轉(zhuǎn)換關(guān)系。為了對(duì)比分析兩種實(shí)驗(yàn)方法的準(zhǔn)確性和穩(wěn)定性,分別進(jìn)行了相同樣品的容量法和重量法等溫吸附實(shí)驗(yàn)。測(cè)試結(jié)果表明,低壓時(shí)甲烷在頁(yè)巖中的吸附曲線呈Ⅰ型的吸附曲線特征,但是當(dāng)壓力進(jìn)一步增大后,等溫吸附曲線會(huì)出現(xiàn)下降。頁(yè)巖中超臨界甲烷的等溫吸附曲線在壓力較大時(shí),必然存在下降的趨勢(shì),這并非異�，F(xiàn)象,而是超臨界流體過(guò)剩吸附量的本質(zhì)特征。對(duì)比分析認(rèn)為,在傳感器精度和天平精度經(jīng)過(guò)校準(zhǔn)的情況下,重量法等溫吸附實(shí)驗(yàn)對(duì)實(shí)驗(yàn)參數(shù)和環(huán)境的敏感程度要低于容量法。特別是對(duì)于吸附量較低的泥頁(yè)巖,容量法測(cè)試中引起的誤差大于重量法。在現(xiàn)有技術(shù)水平條件下,認(rèn)為重量法更適用于頁(yè)巖的等溫吸附實(shí)驗(yàn)研究。
[Abstract]:Shale adsorption gas content is the key parameter to accurately evaluate shale gas content and resource potential. At present, isothermal adsorption experiments are usually used to determine the content of shale gas. The isothermal adsorption experiments are mainly divided into volumetric method and gravimetric method. Volumetric method is a commonly used isothermal adsorption experimental method, and the application of gravimetric method is relatively few. This paper analyzes the experimental principle of the two methods. It is considered that both the volumetric method and the gravimetric isotherm adsorption experiment are excess adsorption, and the absolute adsorption can not be measured directly by the experiment. In order to compare and analyze the accuracy and stability of the two experimental methods, the relationship between excess adsorption capacity and absolute adsorption capacity was established. The isothermal adsorption experiments of the same samples by volumetric method and gravimetric method were carried out. The results showed that the adsorption curve of methane in shale at low pressure showed the characteristics of type I adsorption curve, but when the pressure increased further. The isothermal adsorption curve of supercritical methane in shale will decrease when the pressure is high, which is not an abnormal phenomenon. It is the essential characteristic of supercritical fluid excess adsorption. The contrast analysis shows that the sensor precision and balance precision are calibrated. The sensitivity of gravimetric isothermal adsorption test to experimental parameters and environment is lower than that of volumetric method, especially for shale with low adsorption capacity. The error caused by volumetric method is greater than that by gravimetric method. It is considered that the gravimetric method is more suitable for the isothermal adsorption experiment of shale under the condition of prior technical level.
【作者單位】： 中國(guó)石油勘探開(kāi)發(fā)研究院廊坊分院;中國(guó)石油天然氣集團(tuán)公司非常規(guī)油氣重點(diǎn)實(shí)驗(yàn)室;中國(guó)科學(xué)院力學(xué)研究所流固耦合系統(tǒng)力學(xué)重點(diǎn)實(shí)驗(yàn)室;
【基金】：國(guó)家重點(diǎn)基礎(chǔ)研究發(fā)展計(jì)劃項(xiàng)目(2013CB2281)
【分類號(hào)】：TE37;O647.3
【正文快照】： decrease.There is an inevitable downward trend of the isothermal adsorption curve at high pressure,which is not an abnormal phenomenon,but is the essential characteristic of excess adsorption capacityof supercritical methane.Comparative analysis show tha，

本文編號(hào)：1465379