本文選題：地下水　切入點：電噴霧電離源結(jié)合傅立葉變換離子回旋共振質(zhì)譜(ESI　出處：《分析測試學(xué)報》2017年05期 　論文類型：期刊論文

【摘要】：應(yīng)用電噴霧電離源結(jié)合傅立葉變換離子回旋共振質(zhì)譜(ESI FT-ICR MS)對地下水進行分析,基于高精確度的分子量檢測結(jié)果,鑒定出O_x,N_1O_x和N_2O_x3大類,共計27小類含雜原子的化合物。雜原子化合物中O_x類化合物占絕大多數(shù),而含N化合物則以結(jié)合大量氧原子的形式廣泛存在。結(jié)合各類雜原子化合物的等效雙鍵數(shù)(DBE)及碳數(shù)分布,發(fā)現(xiàn)O_x類化合物中存在大量的羧酸結(jié)構(gòu),推測含氮化合物可能來自于O_x類化合物的衍生反應(yīng)。實驗結(jié)果拓寬了對地下水中可溶性有機質(zhì)的認識,為進一步確定其中雜原子化合物的結(jié)構(gòu)類型奠定了基礎(chǔ)。
[Abstract]:The groundwater was analyzed by electrospray ionization source and Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Based on the results of high precision molecular weight detection, the large categories of OXX and N_2O_x3 were identified. A total of 27 small groups of compounds containing hetero atoms. The N-containing compounds are widely present in the form of a large number of oxygen atoms. Combined with the equivalent double bond number (DBE) and the carbon number distribution of various hetero-atomic compounds, it is found that there are a large number of carboxylic acids in the O _ x compounds. It is suggested that the nitrogen-containing compounds may be derived from the derivative reactions of O _ S _ x compounds. The experimental results broaden the understanding of soluble organic matter in groundwater and lay a foundation for further determining the structural types of hetero-atomic compounds.
【作者單位】： 山東省地礦工程勘察院;
【基金】：山東省2015年度31個省級地質(zhì)勘查項目(SDZS-2015-GTT01包號:D3)
【分類號】：O657.63;P641.12
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本文編號：1650352