MW-CNTs/CTBN改性環(huán)氧及CFRP性能研究
發(fā)布時間:2022-11-05 18:07
碳纖維增強塑料(CFRP)是一種復(fù)合材料,其特點為強度和剛度較高,而且重量較輕,從而使其極前途。也是因為這些特性,越來越多結(jié)構(gòu)材料使用CFRP,特別是在航天工業(yè),其重量輕,而具有很強的結(jié)構(gòu)完整性。與金屬不同,復(fù)合材料具有各向異性特性,這意味著FRP在不同方向的行為取決于纖維增強效果而產(chǎn)生不同的結(jié)果,而大凡在X和?平面上,FRP是強的。當(dāng)沒有?平面加固,使?方向缺乏負載阻力,如沖擊。但分層可能發(fā)生在層內(nèi),這嚴重降低了這些復(fù)合材料的性能,特別是抗壓強度。由于用于基質(zhì)的熱固性材料(即環(huán)氧樹脂)的性能,FRP復(fù)合材料也非常脆弱;w的脆性不允許FRP消散沖擊能量。因此,提高基體的韌性能夠提高FRP從低能量沖擊中吸收沖擊能量的能力。為了提高抵抗低能沖擊的分層能力,首先認為提高環(huán)氧樹脂基體的韌性就會解決這件問題,還研究了斷裂面的微結(jié)構(gòu)以及增韌機理。新增橡膠改性環(huán)氧樹脂也是一種提高韌性的方法,而建立了橡膠改性環(huán)氧樹脂的基礎(chǔ)。同時加入少量的橡膠,從而提高不穩(wěn)定機械性能的韌性。近年來,對碳納米管(CNTs)改性環(huán)氧樹脂已經(jīng)有許多科學(xué)家研究。CNTs具有較高的比強度和剛度,并且相信能夠提高韌性而不降低環(huán)氧...
【文章頁數(shù)】:76 頁
【學(xué)位級別】:碩士
【文章目錄】:
詳細摘要
Abstract
Chapter 1 Introduction
1.1 Preface
1.2 Review
1.2.1 General Introduction to Composites
1.2.2 Delamination and Impact resistance
1.3 Epoxy Resin Toughening
1.3.1 Toughened by CTBN
1.3.2 Toughened by Carbon nanotubes
1.4 Research Content
Chapter 2 Methodology
2.1 Preface
2.2 Fabrication
2.2.1 Materials
2.2.2 Production of CTBN and MW-CNTs modified epoxy resin
2.2.3 Production of CFRP with binary modified epoxy
2.3 Experimental test equipment
2.3.1 Tensile Test
2.3.2 Three-point bending
2.3.3 Low energy impact
2.3.4 Compression after Impact
2.3.5 Optical Microscope
2.3.6 Scanning Electron Microscopy
Chapter 3 Effect of CTBN and MW-CNTs on epoxy resin
3.1 Preface
3.2 Mechanical Properties
3.3 The effect of CTBN on epoxy resin
3.3.1 Tension property of CTBN modified Epoxy
3.3.2 Flexural property of CTBN modified epoxy
3.3.3 SEM imaging of CTBN modified epoxy
3.4 The effect of MW-CNTs on epoxy resin
3.4.1 Tension property of MW-CNTs modified epoxy
3.4.2 Flexural property of MW-CNTs modified epoxy
3.4.3 SEM imaging of pullout MW-CNTs
3.4.4 SEM imaging of MW-CNTs agglomerate
3.5 The effect of CTBN and MW-CNTs on epoxy resin
3.5.1 Tension property of several modified epoxy
3.5.2 Flexural property of several modified epoxy
3.5.3 SEM imaging of several modified epoxy
3.6 The effect of dispersing MW-CNTs on binary modified epoxy
3.6.1 Tension property of binary modified epoxy
3.6.2 Flexural property of binary modified epoxy
3.6.3 SEM imaging of binary modified epoxy
3.7 Summary
Chapter 4 Effect of CTBN and MW-CNTs on CFRP
4.1 Preface
4.2 Mechanical properties of CFRP
4.2.1 Tension Property of CFRP
4.2.2 Flexural Property of CFRP
4.3 SEM Imaging of CFRP
4.4 Low Energy Impact and Compression after Impact of CFRP
4.4.1 Low energy impact
4.4.2 Compression after Impact (CAI)
4.5 Summary
Conclusion
References
Acknowledgement
【參考文獻】:
期刊論文
[1]Microstructure and flexural properties of carbon/carbon composite with in-situ grown carbon nanotube as secondary reinforcement[J]. Hai Zhang,Lingjun Guo,Qiang Song,Qiangang Fu,Hejun Li,Kezhi Li. Progress in Natural Science:Materials International. 2013(02)
本文編號:3703078
【文章頁數(shù)】:76 頁
【學(xué)位級別】:碩士
【文章目錄】:
詳細摘要
Abstract
Chapter 1 Introduction
1.1 Preface
1.2 Review
1.2.1 General Introduction to Composites
1.2.2 Delamination and Impact resistance
1.3 Epoxy Resin Toughening
1.3.1 Toughened by CTBN
1.3.2 Toughened by Carbon nanotubes
1.4 Research Content
Chapter 2 Methodology
2.1 Preface
2.2 Fabrication
2.2.1 Materials
2.2.2 Production of CTBN and MW-CNTs modified epoxy resin
2.2.3 Production of CFRP with binary modified epoxy
2.3 Experimental test equipment
2.3.1 Tensile Test
2.3.2 Three-point bending
2.3.3 Low energy impact
2.3.4 Compression after Impact
2.3.5 Optical Microscope
2.3.6 Scanning Electron Microscopy
Chapter 3 Effect of CTBN and MW-CNTs on epoxy resin
3.1 Preface
3.2 Mechanical Properties
3.3 The effect of CTBN on epoxy resin
3.3.1 Tension property of CTBN modified Epoxy
3.3.2 Flexural property of CTBN modified epoxy
3.3.3 SEM imaging of CTBN modified epoxy
3.4 The effect of MW-CNTs on epoxy resin
3.4.1 Tension property of MW-CNTs modified epoxy
3.4.2 Flexural property of MW-CNTs modified epoxy
3.4.3 SEM imaging of pullout MW-CNTs
3.4.4 SEM imaging of MW-CNTs agglomerate
3.5 The effect of CTBN and MW-CNTs on epoxy resin
3.5.1 Tension property of several modified epoxy
3.5.2 Flexural property of several modified epoxy
3.5.3 SEM imaging of several modified epoxy
3.6 The effect of dispersing MW-CNTs on binary modified epoxy
3.6.1 Tension property of binary modified epoxy
3.6.2 Flexural property of binary modified epoxy
3.6.3 SEM imaging of binary modified epoxy
3.7 Summary
Chapter 4 Effect of CTBN and MW-CNTs on CFRP
4.1 Preface
4.2 Mechanical properties of CFRP
4.2.1 Tension Property of CFRP
4.2.2 Flexural Property of CFRP
4.3 SEM Imaging of CFRP
4.4 Low Energy Impact and Compression after Impact of CFRP
4.4.1 Low energy impact
4.4.2 Compression after Impact (CAI)
4.5 Summary
Conclusion
References
Acknowledgement
【參考文獻】:
期刊論文
[1]Microstructure and flexural properties of carbon/carbon composite with in-situ grown carbon nanotube as secondary reinforcement[J]. Hai Zhang,Lingjun Guo,Qiang Song,Qiangang Fu,Hejun Li,Kezhi Li. Progress in Natural Science:Materials International. 2013(02)
本文編號:3703078
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